Synthesis and characterization of a novel open-framework nickel-zinc phosphite with intersecting three-dimensional 16-ring channels

Zhi En Lin; Jie Zhang; Shou Tian Zheng; Guo Yu Yang

doi:10.1039/b402321h

Synthesis and characterization of a novel open-framework nickel-zinc phosphite with intersecting three-dimensional 16-ring channels

Zhi En Lin, Jie Zhang, Shou Tian Zheng, Guo Yu Yang^*

^*此作品的通讯作者

科研成果: 期刊稿件 › 文章 › 同行评审

49 引用（Scopus）

摘要

A new inorganic-organic hybrid solid, Ni(DETA)(H₂O)Zn ₂(HPO₃)₃ (FJ-14), has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, thermogravimetric analysis and magnetic susceptibility measurements. The compound is novel in the sense that it represents the first example of open- framework bimetallic phosphite. The structure of the compound consists of strictly alternating ZnO₄ and HPO₃ polyhedra through their vertices, forming zinc phosphite layers parallel to the bc plane. These layers are further pillared by Ni₂(DETA)₂(H₂O) ₂O₂ dinuclear units to generate a 3D framework with intersecting three-dimensional 16-ring channels.

源语言	英语
页（从-至）	1652-1655
页数	4
期刊	Journal of Materials Chemistry
卷	14
期	10
DOI	https://doi.org/10.1039/b402321h
出版状态	已出版 - 21 5月 2004
已对外发布	是

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title = "Synthesis and characterization of a novel open-framework nickel-zinc phosphite with intersecting three-dimensional 16-ring channels",

abstract = "A new inorganic-organic hybrid solid, Ni(DETA)(H2O)Zn 2(HPO3)3 (FJ-14), has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, thermogravimetric analysis and magnetic susceptibility measurements. The compound is novel in the sense that it represents the first example of open- framework bimetallic phosphite. The structure of the compound consists of strictly alternating ZnO4 and HPO3 polyhedra through their vertices, forming zinc phosphite layers parallel to the bc plane. These layers are further pillared by Ni2(DETA)2(H2O) 2O2 dinuclear units to generate a 3D framework with intersecting three-dimensional 16-ring channels.",

author = "Lin, {Zhi En} and Jie Zhang and Zheng, {Shou Tian} and Yang, {Guo Yu}",

year = "2004",

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AU - Lin, Zhi En

AU - Zhang, Jie

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2004/5/21

Y1 - 2004/5/21

N2 - A new inorganic-organic hybrid solid, Ni(DETA)(H2O)Zn 2(HPO3)3 (FJ-14), has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, thermogravimetric analysis and magnetic susceptibility measurements. The compound is novel in the sense that it represents the first example of open- framework bimetallic phosphite. The structure of the compound consists of strictly alternating ZnO4 and HPO3 polyhedra through their vertices, forming zinc phosphite layers parallel to the bc plane. These layers are further pillared by Ni2(DETA)2(H2O) 2O2 dinuclear units to generate a 3D framework with intersecting three-dimensional 16-ring channels.

AB - A new inorganic-organic hybrid solid, Ni(DETA)(H2O)Zn 2(HPO3)3 (FJ-14), has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, thermogravimetric analysis and magnetic susceptibility measurements. The compound is novel in the sense that it represents the first example of open- framework bimetallic phosphite. The structure of the compound consists of strictly alternating ZnO4 and HPO3 polyhedra through their vertices, forming zinc phosphite layers parallel to the bc plane. These layers are further pillared by Ni2(DETA)2(H2O) 2O2 dinuclear units to generate a 3D framework with intersecting three-dimensional 16-ring channels.

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Synthesis and characterization of a novel open-framework nickel-zinc phosphite with intersecting three-dimensional 16-ring channels

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