TY - JOUR
T1 - Synthesis and characterization of a new inorganic-organic hybrid open-framework zinc phosphite
T2 - (C6N3H12) 2 · Zn5(HPO3)6
AU - Pan, Jian Xin
AU - Zheng, Shou Tian
AU - Yang, Guo Yu
PY - 2004/10/12
Y1 - 2004/10/12
N2 - A new inorganic-organic hybrid open-framework zinc phosphite, (C 6N3H12)·2 Zn 5(HPO3)6, has been hydrothermally synthesized in the presence of l-(3-aminopropyl)imidazole amine as a structure-directing agent. Its structure was determined by single-crystal X-ray diffraction and further characterized by powder X-ray diffraction (PXRD), IR spectroscopy, ICP, elemental, and TG analyses. This compound crystallizes in the orthorhombic system, space group C2221 (no. 20), a = 9.9512(4), b = 14.7129(6), c = 22.50660(10) Å, V = 3295.21(19) Å3, Z = 4. The connectivity of the strictly alternating Zn-centered tetrahedra and HPO 3 pseudopyramids results in a 3D framework with intersecting 8- and 12-membered ring channels, where organic amines reside. It is worth noting that the title compound is the first metal phosphite to be prepared with a metal: phosphorus ratio of 5:6.
AB - A new inorganic-organic hybrid open-framework zinc phosphite, (C 6N3H12)·2 Zn 5(HPO3)6, has been hydrothermally synthesized in the presence of l-(3-aminopropyl)imidazole amine as a structure-directing agent. Its structure was determined by single-crystal X-ray diffraction and further characterized by powder X-ray diffraction (PXRD), IR spectroscopy, ICP, elemental, and TG analyses. This compound crystallizes in the orthorhombic system, space group C2221 (no. 20), a = 9.9512(4), b = 14.7129(6), c = 22.50660(10) Å, V = 3295.21(19) Å3, Z = 4. The connectivity of the strictly alternating Zn-centered tetrahedra and HPO 3 pseudopyramids results in a 3D framework with intersecting 8- and 12-membered ring channels, where organic amines reside. It is worth noting that the title compound is the first metal phosphite to be prepared with a metal: phosphorus ratio of 5:6.
KW - Crystal structure
KW - Hybrid solid
KW - Hydrothermal synthesis
KW - Open-framework
KW - Zinc phosphite
UR - http://www.scopus.com/inward/record.url?scp=5044241978&partnerID=8YFLogxK
U2 - 10.1016/j.micromeso.2004.07.022
DO - 10.1016/j.micromeso.2004.07.022
M3 - Article
AN - SCOPUS:5044241978
SN - 1387-1811
VL - 75
SP - 129
EP - 133
JO - Microporous and Mesoporous Materials
JF - Microporous and Mesoporous Materials
IS - 1-2
ER -