Syntheses, structures and photoluminescent properties of three d 10 coordination architectures based on in-situ 1,3,5-triazine derivatives

Changyu Xiao, Yamin Li*, Huijie Lun, Caiyan Cui, Yanqing Xu

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

24 引用 (Scopus)

摘要

In the presence of aromatic carboxylic acids, three new d10 transition metal coordination polymers, [Ag(PAHT)]n (1), [Ag 2(HCA)]n (2) and [Cu6(CA)2(H 2O)]n (3) (HPAHT=2-phenyl-4-amino-6-hydroxy-1,3,5- triazine, H3CA=cyanuric acid) have been synthesized based on in-situ 1,3,5-triazine derivatives resulting from 2,4-diamino-6-phenyl-1,3,5-triazine, 2-chloro-4,6-diamino-1,3,5-triazine and melamine under hydrothermal conditions. Complexes 1-3 have been characterized by single-crystal X-ray diffraction, IR spectra, elemental analysis and thermogravimetric analysis (TGA). The compound 1 exhibits a uninodal three-connected 3D network with a rare lig LiGe type topology, which contains right-handed and left-handed [Ag(PAHT)]n helical chains. For compound 2, the 3D network is comprised of 2D sheet by strongly Ag-O and weakly Ag(I).Ag(I) interactions. In compound 3, it is infrequently observed that dodecanuclear copper(I) units as secondary building units (SBUs) construct 3D network by the ligands CA3- with a rare uninodal 10-connected bct topology (312.428.5 5). The photoluminescent properties of three compounds have also been measured.

源语言英语
页(从-至)127-133
页数7
期刊Journal of Solid State Chemistry
208
DOI
出版状态已出版 - 2013
已对外发布

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Xiao, C., Li, Y., Lun, H., Cui, C., & Xu, Y. (2013). Syntheses, structures and photoluminescent properties of three d 10 coordination architectures based on in-situ 1,3,5-triazine derivatives. Journal of Solid State Chemistry, 208, 127-133. https://doi.org/10.1016/j.jssc.2013.10.004