TY - JOUR
T1 - Syntheses, structures and photoluminescent properties of three d 10 coordination architectures based on in-situ 1,3,5-triazine derivatives
AU - Xiao, Changyu
AU - Li, Yamin
AU - Lun, Huijie
AU - Cui, Caiyan
AU - Xu, Yanqing
PY - 2013
Y1 - 2013
N2 - In the presence of aromatic carboxylic acids, three new d10 transition metal coordination polymers, [Ag(PAHT)]n (1), [Ag 2(HCA)]n (2) and [Cu6(CA)2(H 2O)]n (3) (HPAHT=2-phenyl-4-amino-6-hydroxy-1,3,5- triazine, H3CA=cyanuric acid) have been synthesized based on in-situ 1,3,5-triazine derivatives resulting from 2,4-diamino-6-phenyl-1,3,5-triazine, 2-chloro-4,6-diamino-1,3,5-triazine and melamine under hydrothermal conditions. Complexes 1-3 have been characterized by single-crystal X-ray diffraction, IR spectra, elemental analysis and thermogravimetric analysis (TGA). The compound 1 exhibits a uninodal three-connected 3D network with a rare lig LiGe type topology, which contains right-handed and left-handed [Ag(PAHT)]n helical chains. For compound 2, the 3D network is comprised of 2D sheet by strongly Ag-O and weakly Ag(I).Ag(I) interactions. In compound 3, it is infrequently observed that dodecanuclear copper(I) units as secondary building units (SBUs) construct 3D network by the ligands CA3- with a rare uninodal 10-connected bct topology (312.428.5 5). The photoluminescent properties of three compounds have also been measured.
AB - In the presence of aromatic carboxylic acids, three new d10 transition metal coordination polymers, [Ag(PAHT)]n (1), [Ag 2(HCA)]n (2) and [Cu6(CA)2(H 2O)]n (3) (HPAHT=2-phenyl-4-amino-6-hydroxy-1,3,5- triazine, H3CA=cyanuric acid) have been synthesized based on in-situ 1,3,5-triazine derivatives resulting from 2,4-diamino-6-phenyl-1,3,5-triazine, 2-chloro-4,6-diamino-1,3,5-triazine and melamine under hydrothermal conditions. Complexes 1-3 have been characterized by single-crystal X-ray diffraction, IR spectra, elemental analysis and thermogravimetric analysis (TGA). The compound 1 exhibits a uninodal three-connected 3D network with a rare lig LiGe type topology, which contains right-handed and left-handed [Ag(PAHT)]n helical chains. For compound 2, the 3D network is comprised of 2D sheet by strongly Ag-O and weakly Ag(I).Ag(I) interactions. In compound 3, it is infrequently observed that dodecanuclear copper(I) units as secondary building units (SBUs) construct 3D network by the ligands CA3- with a rare uninodal 10-connected bct topology (312.428.5 5). The photoluminescent properties of three compounds have also been measured.
KW - Coordination polymers
KW - Photoluminescent property
KW - Topology
UR - http://www.scopus.com/inward/record.url?scp=84886732628&partnerID=8YFLogxK
U2 - 10.1016/j.jssc.2013.10.004
DO - 10.1016/j.jssc.2013.10.004
M3 - Article
AN - SCOPUS:84886732628
SN - 0022-4596
VL - 208
SP - 127
EP - 133
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
ER -