Syntheses of isocyanates via amines and carbonyl fluoride

Hengdao Quan*, Ni Zhang, Xiaomeng Zhou, Hua Qian, Akira Sekiya

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

18 引用 (Scopus)

摘要

Isocyanates are widely used in many different areas, but the most common synthesis route-phosgene route cannot fit the more and more rigorous restriction of safety and environment. Here, a facile synthesis method of isocyanates via amines and carbonyl fluoride is proven feasibly by expanding its applications to the syntheses of nine different isocyanates. And two differences with the phosgene route are proposed. The reaction could occur under milder conditions and afford isocyanates in good yields, especially for the isocyanates containing electron withdrawing groups. It is appealing for industrial application.

源语言英语
页(从-至)26-30
页数5
期刊Journal of Fluorine Chemistry
176
DOI
出版状态已出版 - 3 6月 2015

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