Syntheses, crystal structures and thermal stability of Co(II) and Zn(II) complexes with ethyl carbazate

Tong Lai Zhang; Jiang Chuang Song; Jian Guo Zhang; Gui Xia Ma; Kai Bei Yu

doi:10.1515/znb-2005-0505

Syntheses, crystal structures and thermal stability of Co(II) and Zn(II) complexes with ethyl carbazate

Tong Lai Zhang^*, Jiang Chuang Song, Jian Guo Zhang, Gui Xia Ma, Kai Bei Yu

^*此作品的通讯作者

机电学院

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摘要

Cobalt(II) and zinc(II) complexes of ethyl carbazate (ECZ), [Co(ECZ) ₃](NO₃)₂ and [Zn(ECZ)₃] (NO ₃ )₂, were synthesized. Single crystals of these two compounds were grown from aqueous solutions using a slow evaporation method. Their structures have been determined by X-ray diffraction analysis. Both of them are monoclinic with space group P2₁/n. The complexes are further characterized by element analysis and IR measurements. Their thermal stabilities are studied by using TG-DTG, DSC techniques. When heated to 350°C, only metal oxide was left for both complexes.

源语言	英语
页（从-至）	505-510
页数	6
期刊	Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
卷	60
期	5
DOI	https://doi.org/10.1515/znb-2005-0505
出版状态	已出版 - 5月 2005

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@article{8e86020d23f04f72b3bc07161bbe9173,

title = "Syntheses, crystal structures and thermal stability of Co(II) and Zn(II) complexes with ethyl carbazate",

abstract = "Cobalt(II) and zinc(II) complexes of ethyl carbazate (ECZ), [Co(ECZ) 3](NO3)2 and [Zn(ECZ)3] (NO 3 )2, were synthesized. Single crystals of these two compounds were grown from aqueous solutions using a slow evaporation method. Their structures have been determined by X-ray diffraction analysis. Both of them are monoclinic with space group P21/n. The complexes are further characterized by element analysis and IR measurements. Their thermal stabilities are studied by using TG-DTG, DSC techniques. When heated to 350°C, only metal oxide was left for both complexes.",

keywords = "Cobalt(II) Complex, Crystal Structure, Ethyl Carbazate, Thermal Stability, Zinc(II) Complex",

author = "Zhang, {Tong Lai} and Song, {Jiang Chuang} and Zhang, {Jian Guo} and Ma, {Gui Xia} and Yu, {Kai Bei}",

year = "2005",

month = may,

doi = "10.1515/znb-2005-0505",

language = "English",

volume = "60",

pages = "505--510",

journal = "Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences",

issn = "0932-0776",

publisher = "Walter de Gruyter GmbH",

number = "5",

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TY - JOUR

T1 - Syntheses, crystal structures and thermal stability of Co(II) and Zn(II) complexes with ethyl carbazate

AU - Zhang, Tong Lai

AU - Song, Jiang Chuang

AU - Zhang, Jian Guo

AU - Ma, Gui Xia

AU - Yu, Kai Bei

PY - 2005/5

Y1 - 2005/5

N2 - Cobalt(II) and zinc(II) complexes of ethyl carbazate (ECZ), [Co(ECZ) 3](NO3)2 and [Zn(ECZ)3] (NO 3 )2, were synthesized. Single crystals of these two compounds were grown from aqueous solutions using a slow evaporation method. Their structures have been determined by X-ray diffraction analysis. Both of them are monoclinic with space group P21/n. The complexes are further characterized by element analysis and IR measurements. Their thermal stabilities are studied by using TG-DTG, DSC techniques. When heated to 350°C, only metal oxide was left for both complexes.

AB - Cobalt(II) and zinc(II) complexes of ethyl carbazate (ECZ), [Co(ECZ) 3](NO3)2 and [Zn(ECZ)3] (NO 3 )2, were synthesized. Single crystals of these two compounds were grown from aqueous solutions using a slow evaporation method. Their structures have been determined by X-ray diffraction analysis. Both of them are monoclinic with space group P21/n. The complexes are further characterized by element analysis and IR measurements. Their thermal stabilities are studied by using TG-DTG, DSC techniques. When heated to 350°C, only metal oxide was left for both complexes.

KW - Cobalt(II) Complex

KW - Crystal Structure

KW - Ethyl Carbazate

KW - Thermal Stability

KW - Zinc(II) Complex

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U2 - 10.1515/znb-2005-0505

DO - 10.1515/znb-2005-0505

M3 - Article

AN - SCOPUS:20444389015

SN - 0932-0776

VL - 60

SP - 505

EP - 510

JO - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

JF - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

IS - 5

ER -

Syntheses, crystal structures and thermal stability of Co(II) and Zn(II) complexes with ethyl carbazate

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