Syntheses, crystal structures and magnetic properties of mixed-valence linear trinuclear cobalt and 2D nickel complexes

Tian Fu Liu*, Zai Xin Wang

*此作品的通讯作者

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摘要

Two new complexes, [CoL2]2[Co(CH3OH) 4] (1), and [Ni2L2(CH3OH) 2]n (2) (H2L = 2-(((2-hydroxynaphthalen-1-yl) methylene)amino)acetic acid), have been synthesized and structurally characterized. Single-crystal X-ray analysis reveals that complex 1 is linear trinuclear mixed valence cobalt complex, while complex 2 is a 2D complex by double naphtholate bridged and syn-anti carboxylate bridged. Magnetic susceptibility measurements indicate that 1 shows mononuclear CoII behavior whereas 2 exhibits an antiferromagnetism behavior.

源语言英语
页(从-至)84-87
页数4
期刊Inorganic Chemistry Communications
30
DOI
出版状态已出版 - 4月 2013

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Liu, T. F., & Wang, Z. X. (2013). Syntheses, crystal structures and magnetic properties of mixed-valence linear trinuclear cobalt and 2D nickel complexes. Inorganic Chemistry Communications, 30, 84-87. https://doi.org/10.1016/j.inoche.2012.12.020