Syntheses and characterizations of three low-dimensional chloride-rich zincophosphates assembled about [d-Co(en)3]3+ and [dl-Co(en)3]3+ complex cations

Peng Chen; Jiyang Li; Fangzheng Duan; Jihong Yu; Ruren Xu; Raj Pal Sharma

doi:10.1021/ic062103+

Syntheses and characterizations of three low-dimensional chloride-rich zincophosphates assembled about [d-Co(en)₃]³⁺ and [dl-Co(en)₃]³⁺ complex cations

Peng Chen, Jiyang Li, Fangzheng Duan, Jihong Yu^*, Ruren Xu, Raj Pal Sharma

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摘要

Three new chloride-rich zincophosphates including two zero-dimensional (0D) clusters [dl-Co(en)₃]₂[Zn₄(H ₂PO₄)2-(HPO₄)₂Cl₈] (denoted ZnPO-CJ33) and [d-Co(en)₃]₂[Zn₄(H ₂PO₄)₂(HPO₄)₂Cl ₈] (denoted ZnPO-CJ34), and one-dimensional (1D) zincophosphate chain [dl-Co(en)₃][Zn₂(H₂PO₄)(HPO ₄)₂Cl₂] (denoted ZnPO-CJ35) have been solvothermally prepared. ZnPO-CJ33 and ZnPO-CJ34 possess the same cluster structure as the macroanionic [Zn₄H₆P₄O ₁₆Cl₈]^6- unit formed by alternation of ZnOCl₃/ZnO₃Cl and HPO₄/H₂PO ₄ tetrahedra but differ in the countercations. The racemic [dl-Co(en)₃]³⁺ cations are located among the clusters of ZnPO-CJ33, whereas chiral [d-Co(en)₃]³⁺ cations are located among the clusters of ZnPO-CJ34. ZnPO-CJ34 templated by the optically pure chiral [d-Co(en)₃]³⁺ cations is the first chiral monomeric zincophosphate. ZnPO-CJ35 templated by the racemic [dl-Co(en) ₃]³⁺ cations possesses a 1D infinite chain structure formed by the alternation of ZnO₃Cl and HPO₄/H ₂PO₄ tetrahedra. The 1D chain structure of ZnPO-CJ35 can also be viewed as generated from the condensation of 0D clusters of ZnPO-CJ33, with the terminal Cl ions replaced by HPO₄ groups. Experimentally, the structural transformation from ZnPO-CJ33 to ZnPO-CJ35 has been investigated.

源语言	英语
页（从-至）	6683-6687
页数	5
期刊	Inorganic Chemistry
卷	46
期	16
DOI	https://doi.org/10.1021/ic062103+
出版状态	已出版 - 6 8月 2007
已对外发布	是

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@article{b1ebea76d20f4a92aa2a3e4bcdcf0bfc,

title = "Syntheses and characterizations of three low-dimensional chloride-rich zincophosphates assembled about [d-Co(en)3]3+ and [dl-Co(en)3]3+ complex cations",

abstract = "Three new chloride-rich zincophosphates including two zero-dimensional (0D) clusters [dl-Co(en)3]2[Zn4(H 2PO4)2-(HPO4)2Cl8] (denoted ZnPO-CJ33) and [d-Co(en)3]2[Zn4(H 2PO4)2(HPO4)2Cl 8] (denoted ZnPO-CJ34), and one-dimensional (1D) zincophosphate chain [dl-Co(en)3][Zn2(H2PO4)(HPO 4)2Cl2] (denoted ZnPO-CJ35) have been solvothermally prepared. ZnPO-CJ33 and ZnPO-CJ34 possess the same cluster structure as the macroanionic [Zn4H6P4O 16Cl8]6- unit formed by alternation of ZnOCl3/ZnO3Cl and HPO4/H2PO 4 tetrahedra but differ in the countercations. The racemic [dl-Co(en)3]3+ cations are located among the clusters of ZnPO-CJ33, whereas chiral [d-Co(en)3]3+ cations are located among the clusters of ZnPO-CJ34. ZnPO-CJ34 templated by the optically pure chiral [d-Co(en)3]3+ cations is the first chiral monomeric zincophosphate. ZnPO-CJ35 templated by the racemic [dl-Co(en) 3]3+ cations possesses a 1D infinite chain structure formed by the alternation of ZnO3Cl and HPO4/H 2PO4 tetrahedra. The 1D chain structure of ZnPO-CJ35 can also be viewed as generated from the condensation of 0D clusters of ZnPO-CJ33, with the terminal Cl ions replaced by HPO4 groups. Experimentally, the structural transformation from ZnPO-CJ33 to ZnPO-CJ35 has been investigated.",

author = "Peng Chen and Jiyang Li and Fangzheng Duan and Jihong Yu and Ruren Xu and Sharma, {Raj Pal}",

year = "2007",

month = aug,

day = "6",

doi = "10.1021/ic062103+",

language = "English",

volume = "46",

pages = "6683--6687",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "16",

}

TY - JOUR

T1 - Syntheses and characterizations of three low-dimensional chloride-rich zincophosphates assembled about [d-Co(en)3]3+ and [dl-Co(en)3]3+ complex cations

AU - Chen, Peng

AU - Li, Jiyang

AU - Duan, Fangzheng

AU - Yu, Jihong

AU - Xu, Ruren

AU - Sharma, Raj Pal

PY - 2007/8/6

Y1 - 2007/8/6

N2 - Three new chloride-rich zincophosphates including two zero-dimensional (0D) clusters [dl-Co(en)3]2[Zn4(H 2PO4)2-(HPO4)2Cl8] (denoted ZnPO-CJ33) and [d-Co(en)3]2[Zn4(H 2PO4)2(HPO4)2Cl 8] (denoted ZnPO-CJ34), and one-dimensional (1D) zincophosphate chain [dl-Co(en)3][Zn2(H2PO4)(HPO 4)2Cl2] (denoted ZnPO-CJ35) have been solvothermally prepared. ZnPO-CJ33 and ZnPO-CJ34 possess the same cluster structure as the macroanionic [Zn4H6P4O 16Cl8]6- unit formed by alternation of ZnOCl3/ZnO3Cl and HPO4/H2PO 4 tetrahedra but differ in the countercations. The racemic [dl-Co(en)3]3+ cations are located among the clusters of ZnPO-CJ33, whereas chiral [d-Co(en)3]3+ cations are located among the clusters of ZnPO-CJ34. ZnPO-CJ34 templated by the optically pure chiral [d-Co(en)3]3+ cations is the first chiral monomeric zincophosphate. ZnPO-CJ35 templated by the racemic [dl-Co(en) 3]3+ cations possesses a 1D infinite chain structure formed by the alternation of ZnO3Cl and HPO4/H 2PO4 tetrahedra. The 1D chain structure of ZnPO-CJ35 can also be viewed as generated from the condensation of 0D clusters of ZnPO-CJ33, with the terminal Cl ions replaced by HPO4 groups. Experimentally, the structural transformation from ZnPO-CJ33 to ZnPO-CJ35 has been investigated.

AB - Three new chloride-rich zincophosphates including two zero-dimensional (0D) clusters [dl-Co(en)3]2[Zn4(H 2PO4)2-(HPO4)2Cl8] (denoted ZnPO-CJ33) and [d-Co(en)3]2[Zn4(H 2PO4)2(HPO4)2Cl 8] (denoted ZnPO-CJ34), and one-dimensional (1D) zincophosphate chain [dl-Co(en)3][Zn2(H2PO4)(HPO 4)2Cl2] (denoted ZnPO-CJ35) have been solvothermally prepared. ZnPO-CJ33 and ZnPO-CJ34 possess the same cluster structure as the macroanionic [Zn4H6P4O 16Cl8]6- unit formed by alternation of ZnOCl3/ZnO3Cl and HPO4/H2PO 4 tetrahedra but differ in the countercations. The racemic [dl-Co(en)3]3+ cations are located among the clusters of ZnPO-CJ33, whereas chiral [d-Co(en)3]3+ cations are located among the clusters of ZnPO-CJ34. ZnPO-CJ34 templated by the optically pure chiral [d-Co(en)3]3+ cations is the first chiral monomeric zincophosphate. ZnPO-CJ35 templated by the racemic [dl-Co(en) 3]3+ cations possesses a 1D infinite chain structure formed by the alternation of ZnO3Cl and HPO4/H 2PO4 tetrahedra. The 1D chain structure of ZnPO-CJ35 can also be viewed as generated from the condensation of 0D clusters of ZnPO-CJ33, with the terminal Cl ions replaced by HPO4 groups. Experimentally, the structural transformation from ZnPO-CJ33 to ZnPO-CJ35 has been investigated.

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U2 - 10.1021/ic062103+

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 16

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Syntheses and characterizations of three low-dimensional chloride-rich zincophosphates assembled about [d-Co(en)3]3+ and [dl-Co(en)3]3+ complex cations

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Syntheses and characterizations of three low-dimensional chloride-rich zincophosphates assembled about [d-Co(en)₃]³⁺ and [dl-Co(en)₃]³⁺ complex cations