Supramolecular structured hydrogel preparation based on self-assemblies of photocurable star-shaped macromers with α-cyclodextrins

Hongliang Wei; Al Ying Zhang; Lijun Qian; Huaiqing Yu; Dandan Hou; Rongxin Qiu; Zeng Guo Feng

doi:10.1002/pola.20773

Supramolecular structured hydrogel preparation based on self-assemblies of photocurable star-shaped macromers with α-cyclodextrins

Hongliang Wei, Al Ying Zhang, Lijun Qian, Huaiqing Yu, Dandan Hou, Rongxin Qiu, Zeng Guo Feng^*

^*此作品的通讯作者

材料学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

35 引用（Scopus）

摘要

A new gelation process during self assemblies of methacryol terminated poly(L-lactide)-b-poly(ethylene glycol) (PLA-b-PEG) copolymers containing three or four arms with α-CDs was investigated. Hydroxyl-terminated star-shaped copolymers of PLA-b-PEG were synthesized in toluene by a ring-opening polymerization of LA with 3A-PEG or 4A-PEG as an initiator and Sn(Oct) ₂ as a catalyst. Soluble macromers bearing methacryloyl terminals were prepared through the reaction of PLA-b-PEG copolymers with methacrylic anhydride in toluene. The results showed that these gels can be photopolymerized, when exposed to ultraviolet light in the presence of a photoinitiator, to produce biodegradable supramolecular structured hydrogels.

源语言	英语
页（从-至）	2941-2949
页数	9
期刊	Journal of Polymer Science, Part A: Polymer Chemistry
卷	43
期	13
DOI	https://doi.org/10.1002/pola.20773
出版状态	已出版 - 1 7月 2005

访问文件

10.1002/pola.20773

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{bc74a7dbc7c949808ccc0b1388f6d9cc,

title = "Supramolecular structured hydrogel preparation based on self-assemblies of photocurable star-shaped macromers with α-cyclodextrins",

abstract = "A new gelation process during self assemblies of methacryol terminated poly(L-lactide)-b-poly(ethylene glycol) (PLA-b-PEG) copolymers containing three or four arms with α-CDs was investigated. Hydroxyl-terminated star-shaped copolymers of PLA-b-PEG were synthesized in toluene by a ring-opening polymerization of LA with 3A-PEG or 4A-PEG as an initiator and Sn(Oct) 2 as a catalyst. Soluble macromers bearing methacryloyl terminals were prepared through the reaction of PLA-b-PEG copolymers with methacrylic anhydride in toluene. The results showed that these gels can be photopolymerized, when exposed to ultraviolet light in the presence of a photoinitiator, to produce biodegradable supramolecular structured hydrogels.",

keywords = "Cyclodextrins, Hydrogels, Photopolymerization, Star-shaped macromers",

author = "Hongliang Wei and Zhang, {Al Ying} and Lijun Qian and Huaiqing Yu and Dandan Hou and Rongxin Qiu and Feng, {Zeng Guo}",

year = "2005",

month = jul,

day = "1",

doi = "10.1002/pola.20773",

language = "English",

volume = "43",

pages = "2941--2949",

journal = "Journal of Polymer Science, Part A: Polymer Chemistry",

issn = "0887-624X",

publisher = "John Wiley & Sons Inc.",

number = "13",

}

TY - JOUR

T1 - Supramolecular structured hydrogel preparation based on self-assemblies of photocurable star-shaped macromers with α-cyclodextrins

AU - Wei, Hongliang

AU - Zhang, Al Ying

AU - Qian, Lijun

AU - Yu, Huaiqing

AU - Hou, Dandan

AU - Qiu, Rongxin

AU - Feng, Zeng Guo

PY - 2005/7/1

Y1 - 2005/7/1

N2 - A new gelation process during self assemblies of methacryol terminated poly(L-lactide)-b-poly(ethylene glycol) (PLA-b-PEG) copolymers containing three or four arms with α-CDs was investigated. Hydroxyl-terminated star-shaped copolymers of PLA-b-PEG were synthesized in toluene by a ring-opening polymerization of LA with 3A-PEG or 4A-PEG as an initiator and Sn(Oct) 2 as a catalyst. Soluble macromers bearing methacryloyl terminals were prepared through the reaction of PLA-b-PEG copolymers with methacrylic anhydride in toluene. The results showed that these gels can be photopolymerized, when exposed to ultraviolet light in the presence of a photoinitiator, to produce biodegradable supramolecular structured hydrogels.

AB - A new gelation process during self assemblies of methacryol terminated poly(L-lactide)-b-poly(ethylene glycol) (PLA-b-PEG) copolymers containing three or four arms with α-CDs was investigated. Hydroxyl-terminated star-shaped copolymers of PLA-b-PEG were synthesized in toluene by a ring-opening polymerization of LA with 3A-PEG or 4A-PEG as an initiator and Sn(Oct) 2 as a catalyst. Soluble macromers bearing methacryloyl terminals were prepared through the reaction of PLA-b-PEG copolymers with methacrylic anhydride in toluene. The results showed that these gels can be photopolymerized, when exposed to ultraviolet light in the presence of a photoinitiator, to produce biodegradable supramolecular structured hydrogels.

KW - Cyclodextrins

KW - Hydrogels

KW - Photopolymerization

KW - Star-shaped macromers

UR - http://www.scopus.com/inward/record.url?scp=24344437735&partnerID=8YFLogxK

U2 - 10.1002/pola.20773

DO - 10.1002/pola.20773

M3 - Article

AN - SCOPUS:24344437735

SN - 0887-624X

VL - 43

SP - 2941

EP - 2949

JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

IS - 13

ER -

Supramolecular structured hydrogel preparation based on self-assemblies of photocurable star-shaped macromers with α-cyclodextrins

摘要

访问文件

其它文件与链接

指纹

引用此