Sulfate ion encapsulation in caged supramolecular structures assembled by second-sphere coordination

Biao Wu; Jianjun Liang; Jin Yang; Chuandong Jia; Xiao Juan Yang; Hongrui Zhang; Ning Tang; Christoph Janiak

doi:10.1039/b719019k

Sulfate ion encapsulation in caged supramolecular structures assembled by second-sphere coordination

Biao Wu^*, Jianjun Liang, Jin Yang, Chuandong Jia, Xiao Juan Yang, Hongrui Zhang, Ning Tang, Christoph Janiak

^*此作品的通讯作者

科研成果: 期刊稿件 › 文章 › 同行评审

169 引用（Scopus）

摘要

A tripodal tris(3-pyridylurea) receptor (L) assembles with metal sulfate salts MSO₄ (M = Mn, Zn) to afford supramolecular cages [SO ₄⊂L₂] that encapsulate the SO₄^2- ion via multiple hydrogen bonds in a three-dimensional structure held by second-sphere coordination; ¹H NMR and negative-ion mode ESI-MS spectra reveal significantly strong sulfate binding in solution.

源语言	英语
页（从-至）	1762-1764
页数	3
期刊	Chemical Communications
期	15
DOI	https://doi.org/10.1039/b719019k
出版状态	已出版 - 2008
已对外发布	是

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title = "Sulfate ion encapsulation in caged supramolecular structures assembled by second-sphere coordination",

abstract = "A tripodal tris(3-pyridylurea) receptor (L) assembles with metal sulfate salts MSO4 (M = Mn, Zn) to afford supramolecular cages [SO 4⊂L2] that encapsulate the SO42- ion via multiple hydrogen bonds in a three-dimensional structure held by second-sphere coordination; 1H NMR and negative-ion mode ESI-MS spectra reveal significantly strong sulfate binding in solution.",

author = "Biao Wu and Jianjun Liang and Jin Yang and Chuandong Jia and Yang, {Xiao Juan} and Hongrui Zhang and Ning Tang and Christoph Janiak",

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T1 - Sulfate ion encapsulation in caged supramolecular structures assembled by second-sphere coordination

AU - Wu, Biao

AU - Liang, Jianjun

AU - Yang, Jin

AU - Jia, Chuandong

AU - Yang, Xiao Juan

AU - Zhang, Hongrui

AU - Tang, Ning

AU - Janiak, Christoph

PY - 2008

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N2 - A tripodal tris(3-pyridylurea) receptor (L) assembles with metal sulfate salts MSO4 (M = Mn, Zn) to afford supramolecular cages [SO 4⊂L2] that encapsulate the SO42- ion via multiple hydrogen bonds in a three-dimensional structure held by second-sphere coordination; 1H NMR and negative-ion mode ESI-MS spectra reveal significantly strong sulfate binding in solution.

AB - A tripodal tris(3-pyridylurea) receptor (L) assembles with metal sulfate salts MSO4 (M = Mn, Zn) to afford supramolecular cages [SO 4⊂L2] that encapsulate the SO42- ion via multiple hydrogen bonds in a three-dimensional structure held by second-sphere coordination; 1H NMR and negative-ion mode ESI-MS spectra reveal significantly strong sulfate binding in solution.

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DO - 10.1039/b719019k

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Sulfate ion encapsulation in caged supramolecular structures assembled by second-sphere coordination

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