TY - JOUR
T1 - Study on two coordination compounds using semicarbazide (SCZ) as bidentate ligand
T2 - [Ni(SCZ)3](NO3)2 and Cu(SCZ) 2Cl2
AU - Guo, Jin Yu
AU - Ma, Gui Xia
AU - Zhang, Tong Lai
AU - Zhang, Jian Guo
AU - Liu, Yan Hong
PY - 2007/5
Y1 - 2007/5
N2 - Two coordination compounds have been synthesized using semicarbazide as ligand- [Ni(SCZ)3](NO3)2 (1) and Cu(SCZ) 2Cl2 (2). (1) crystallized as the monoclinic, P2(1)/c space group, a = 10.832(2) Å, b = 9.980(2) Å, c = 13.801(3) Å, β = 102.89(3)°; (2) crystallized as the monoclinic, P2(1)/c space group, a = 7.541(1) Å, b = 9.275(1) Å, c = 6.875(1) Å, β = 101.48(1)°. In both compounds, semicarbazides coordinate to nickel(II) or copper(II) centers to form the 5-member ring system. With the intermolecular hydrogen bonds, molecules are linked together to form the three-dimensional packing diagrams. Thermal decomposition mechanisms of both compounds were predicted based on DSC, TG-DTG and FTIR analyses.
AB - Two coordination compounds have been synthesized using semicarbazide as ligand- [Ni(SCZ)3](NO3)2 (1) and Cu(SCZ) 2Cl2 (2). (1) crystallized as the monoclinic, P2(1)/c space group, a = 10.832(2) Å, b = 9.980(2) Å, c = 13.801(3) Å, β = 102.89(3)°; (2) crystallized as the monoclinic, P2(1)/c space group, a = 7.541(1) Å, b = 9.275(1) Å, c = 6.875(1) Å, β = 101.48(1)°. In both compounds, semicarbazides coordinate to nickel(II) or copper(II) centers to form the 5-member ring system. With the intermolecular hydrogen bonds, molecules are linked together to form the three-dimensional packing diagrams. Thermal decomposition mechanisms of both compounds were predicted based on DSC, TG-DTG and FTIR analyses.
UR - http://www.scopus.com/inward/record.url?scp=34249005617&partnerID=8YFLogxK
U2 - 10.1007/s11243-006-0154-6
DO - 10.1007/s11243-006-0154-6
M3 - Article
AN - SCOPUS:34249005617
SN - 0340-4285
VL - 32
SP - 413
EP - 418
JO - Transition Metal Chemistry
JF - Transition Metal Chemistry
IS - 4
ER -