Study on the synthesis of toluene-2,4-diisocyanate via amine and carbonyl fluoride

Ni Zhang, Xiaomeng Zhou, Hengdao Quan*, Akira Sekiya

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

11 引用 (Scopus)

摘要

Abstract We presented recently a synthesis of toluene-2,4-diisocyanate (TDI) as one of the nine examples to verify the feasibility of an industrial appealing two-step method for isocyanates synthesis via amines and carbonyl fluoride (COF2). Because more investigation was considered to be necessary for future industrial application, the two-step synthesis processes of TDI were studied in detail herein. The total yield of TDI increased 5.6% under the optimized experimental conditions. The influence of the excess COF2 left in the reaction system was studied carefully according to a one-pot method.

源语言英语
文章编号8626
页(从-至)208-213
页数6
期刊Journal of Fluorine Chemistry
178
DOI
出版状态已出版 - 1 10月 2015

指纹

探究 'Study on the synthesis of toluene-2,4-diisocyanate via amine and carbonyl fluoride' 的科研主题。它们共同构成独一无二的指纹。

引用此