Study on the preparation of Al/CuO composites and its thermal properties

Wei Kang Wang; Jian Min Li; Rong Jie Yang

doi:10.7673/j.issn.1006-2793.2016.06.009

Study on the preparation of Al/CuO composites and its thermal properties

Wei Kang Wang, Jian Min Li^*, Rong Jie Yang

^*此作品的通讯作者

材料学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

2 引用（Scopus）

摘要

Al/CuO composite was fabricated by high-energy ball milling. Phase structure and morphology were inspected using scanning electron microscopy (SEM), particle size analyzer, X-ray diffraction (XRD), and thermal properties were investigated by thermogravimetry-differential scanning calorimetry (TG-DSC). The results show that microscopic morphology of Al/CuO composite is sheet, particle size increases while grain size is refined into micrometer scale. Moreover, thermal properties of Al/CuO composite reacted with air are significantly improved, and reach a peak value when Al/CuO was milled for 3 h. The weight increase of Al/CuO composite and reactivity of Al is up to 74.33% and 92.91%, respectively. The maximum heat flow rate (Q_max) is increased by 53 W/g. Al/CuO-O₂ system exhibits an intense exothermic peak with reaction heat of 3 095.62 J/g. Finally, A low activation energy merely with 202.7 kJ/mol can be obtained, Which shows important values in the application of energetic materials.

源语言	英语
页（从-至）	784-788 and 796
期刊	Guti Huojian Jishu/Journal of Solid Rocket Technology
卷	39
期	6
DOI	https://doi.org/10.7673/j.issn.1006-2793.2016.06.009
出版状态	已出版 - 1 12月 2016

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title = "Study on the preparation of Al/CuO composites and its thermal properties",

abstract = "Al/CuO composite was fabricated by high-energy ball milling. Phase structure and morphology were inspected using scanning electron microscopy (SEM), particle size analyzer, X-ray diffraction (XRD), and thermal properties were investigated by thermogravimetry-differential scanning calorimetry (TG-DSC). The results show that microscopic morphology of Al/CuO composite is sheet, particle size increases while grain size is refined into micrometer scale. Moreover, thermal properties of Al/CuO composite reacted with air are significantly improved, and reach a peak value when Al/CuO was milled for 3 h. The weight increase of Al/CuO composite and reactivity of Al is up to 74.33% and 92.91%, respectively. The maximum heat flow rate (Qmax) is increased by 53 W/g. Al/CuO-O2 system exhibits an intense exothermic peak with reaction heat of 3 095.62 J/g. Finally, A low activation energy merely with 202.7 kJ/mol can be obtained, Which shows important values in the application of energetic materials.",

keywords = "Al/CuO composites, High-energy milling method, Thermal properties",

author = "Wang, {Wei Kang} and Li, {Jian Min} and Yang, {Rong Jie}",

year = "2016",

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day = "1",

doi = "10.7673/j.issn.1006-2793.2016.06.009",

language = "English",

volume = "39",

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TY - JOUR

T1 - Study on the preparation of Al/CuO composites and its thermal properties

AU - Wang, Wei Kang

AU - Li, Jian Min

AU - Yang, Rong Jie

PY - 2016/12/1

Y1 - 2016/12/1

N2 - Al/CuO composite was fabricated by high-energy ball milling. Phase structure and morphology were inspected using scanning electron microscopy (SEM), particle size analyzer, X-ray diffraction (XRD), and thermal properties were investigated by thermogravimetry-differential scanning calorimetry (TG-DSC). The results show that microscopic morphology of Al/CuO composite is sheet, particle size increases while grain size is refined into micrometer scale. Moreover, thermal properties of Al/CuO composite reacted with air are significantly improved, and reach a peak value when Al/CuO was milled for 3 h. The weight increase of Al/CuO composite and reactivity of Al is up to 74.33% and 92.91%, respectively. The maximum heat flow rate (Qmax) is increased by 53 W/g. Al/CuO-O2 system exhibits an intense exothermic peak with reaction heat of 3 095.62 J/g. Finally, A low activation energy merely with 202.7 kJ/mol can be obtained, Which shows important values in the application of energetic materials.

AB - Al/CuO composite was fabricated by high-energy ball milling. Phase structure and morphology were inspected using scanning electron microscopy (SEM), particle size analyzer, X-ray diffraction (XRD), and thermal properties were investigated by thermogravimetry-differential scanning calorimetry (TG-DSC). The results show that microscopic morphology of Al/CuO composite is sheet, particle size increases while grain size is refined into micrometer scale. Moreover, thermal properties of Al/CuO composite reacted with air are significantly improved, and reach a peak value when Al/CuO was milled for 3 h. The weight increase of Al/CuO composite and reactivity of Al is up to 74.33% and 92.91%, respectively. The maximum heat flow rate (Qmax) is increased by 53 W/g. Al/CuO-O2 system exhibits an intense exothermic peak with reaction heat of 3 095.62 J/g. Finally, A low activation energy merely with 202.7 kJ/mol can be obtained, Which shows important values in the application of energetic materials.

KW - Al/CuO composites

KW - High-energy milling method

KW - Thermal properties

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U2 - 10.7673/j.issn.1006-2793.2016.06.009

DO - 10.7673/j.issn.1006-2793.2016.06.009

M3 - Article

AN - SCOPUS:85014184889

SN - 1006-2793

VL - 39

SP - 784-788 and 796

JO - Guti Huojian Jishu/Journal of Solid Rocket Technology

JF - Guti Huojian Jishu/Journal of Solid Rocket Technology

IS - 6

ER -

Study on the preparation of Al/CuO composites and its thermal properties

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