Structure and magnetic property of bimetallic hexanuclear cluster based on 5-chlorosalicylaldehyde oxime

Yuan Zhang, Chen Yan Wei, Tian Fu Liu*

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

1 引用 (Scopus)

摘要

The bimetallic hexanuclear cluster [Mn4Ni2O 2(Cl-Sao)6·(CH3OH)8] ·10CH3OH (1) was synthesized. Single-crystal X-ray analysis reveals that 1 consists of two [Mn2Ni(μ3-O)(Cl-Sao) 3] subunits linked together via two pairs of long NiO bonds involving two oximate oxygen atoms and two phenolate oxygen atoms. Each Mn and Ni center achieves six-coordination with axial methanol molecules. The spin centers of the MnIII and NiII ions exchange magnetic coupling through O2-, O-phenolate and NO bridges. The magnetic properties of the cluster have been investigated.

源语言英语
页(从-至)937-940
页数4
期刊Chinese Chemical Letters
25
6
DOI
出版状态已出版 - 6月 2014

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Zhang, Y., Wei, C. Y., & Liu, T. F. (2014). Structure and magnetic property of bimetallic hexanuclear cluster based on 5-chlorosalicylaldehyde oxime. Chinese Chemical Letters, 25(6), 937-940. https://doi.org/10.1016/j.cclet.2014.01.009