摘要
The bimetallic hexanuclear cluster [Mn4Ni2O 2(Cl-Sao)6·(CH3OH)8] ·10CH3OH (1) was synthesized. Single-crystal X-ray analysis reveals that 1 consists of two [Mn2Ni(μ3-O)(Cl-Sao) 3] subunits linked together via two pairs of long NiO bonds involving two oximate oxygen atoms and two phenolate oxygen atoms. Each Mn and Ni center achieves six-coordination with axial methanol molecules. The spin centers of the MnIII and NiII ions exchange magnetic coupling through O2-, O-phenolate and NO bridges. The magnetic properties of the cluster have been investigated.
源语言 | 英语 |
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页(从-至) | 937-940 |
页数 | 4 |
期刊 | Chinese Chemical Letters |
卷 | 25 |
期 | 6 |
DOI | |
出版状态 | 已出版 - 6月 2014 |
指纹
探究 'Structure and magnetic property of bimetallic hexanuclear cluster based on 5-chlorosalicylaldehyde oxime' 的科研主题。它们共同构成独一无二的指纹。引用此
Zhang, Y., Wei, C. Y., & Liu, T. F. (2014). Structure and magnetic property of bimetallic hexanuclear cluster based on 5-chlorosalicylaldehyde oxime. Chinese Chemical Letters, 25(6), 937-940. https://doi.org/10.1016/j.cclet.2014.01.009