Structural phase separation in K 0.8Fe 1.6+xSe 2 superconductors

Zhi Wei Wang, Zhen Wang, Yuan Jun Song, Chao Ma, Yao Cai, Zhen Chen, Huan Fang Tian, Huai Xin Yang, Gen Fu Chen, Jian Qi Li*

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摘要

Structural investigations on the K 0.8Fe 1.6+xSe 2 superconducting materials have revealed microstripes arising from phase separation. Two coexisting structural phases can be characterized by modulations of q 1 = 1/5[3a * + b *], the antiferromagnetic phase K 0.8Fe 1.6+xSe 2, and q 2 = 1/2[a * + b *], the superconducting phase K yFe 2Se 2, respectively. These stripe patterns also show visible correlation with the anisotropic assembly of superconducting particles along the [110] and [11̄0] directions. In addition to the notable stripe structures, a nanoscale phase separation also appears in the present superconducting system as clearly observed by high-resolution transmission electron microscopy. Certain nanoscale structural features in this heterogeneous system can be qualitatively understood by the percolation scenario.

源语言英语
页(从-至)17847-17852
页数6
期刊Journal of Physical Chemistry C
116
33
DOI
出版状态已出版 - 23 8月 2012
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Wang, Z. W., Wang, Z., Song, Y. J., Ma, C., Cai, Y., Chen, Z., Tian, H. F., Yang, H. X., Chen, G. F., & Li, J. Q. (2012). Structural phase separation in K 0.8Fe 1.6+xSe 2 superconductors. Journal of Physical Chemistry C, 116(33), 17847-17852. https://doi.org/10.1021/jp306310m