TY - JOUR
T1 - Structural characterization and process optimization of bistetrazolohydrazine
AU - Meng, Ling Qiao
AU - Du, Zhi Ming
AU - He, Chun Lin
AU - Zhao, Lin Shuang
AU - Cong, Xiao Min
AU - Li, Fang
PY - 2010
Y1 - 2010
N2 - Disodium 5, 5'-hydrazinotetrazolate was prepared with the starting materials, sodium 5, 5'azotetrazolate as well as magnesium, and the fianl product,bistetrazolohydrazine (HBT) was synthesized through hydrochloric acid and sodium 5,5'-hydrazinotetrazolate. The target product HBT was characterized by elemental analysis, IR, HNMR,SEM and TG-DSC. The factors affecting the yield, including reaction mole ratio, reaction time, reaction temperature, HCl mass fraction were investigated. The optimum reaction conditions are reactant mole ratio n(Na2ZT) : n(Mg) =1 : 6, reaction time 6 hour, reaction temperature 100°C and HCl mass fraction, 20%, the highest yield of the HBT is 91. 53%.
AB - Disodium 5, 5'-hydrazinotetrazolate was prepared with the starting materials, sodium 5, 5'azotetrazolate as well as magnesium, and the fianl product,bistetrazolohydrazine (HBT) was synthesized through hydrochloric acid and sodium 5,5'-hydrazinotetrazolate. The target product HBT was characterized by elemental analysis, IR, HNMR,SEM and TG-DSC. The factors affecting the yield, including reaction mole ratio, reaction time, reaction temperature, HCl mass fraction were investigated. The optimum reaction conditions are reactant mole ratio n(Na2ZT) : n(Mg) =1 : 6, reaction time 6 hour, reaction temperature 100°C and HCl mass fraction, 20%, the highest yield of the HBT is 91. 53%.
KW - Bistetrazolohydrazine
KW - Characterization
KW - Nitrogen-rich compounds
KW - Organic chemistry
KW - Synthesis
UR - http://www.scopus.com/inward/record.url?scp=78650455130&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:78650455130
SN - 1007-7812
VL - 33
SP - 15
EP - 18
JO - Huozhayao Xuebao/Chinese Journal of Explosives and Propellants
JF - Huozhayao Xuebao/Chinese Journal of Explosives and Propellants
IS - 5
ER -