Stability and electrochemical properties of full-conjugated self-assembled films based on polyaniline and its acid-substituted derivates

Miao Miao Xiao; Bin Tong; Wei Zhao; Jian Bing Shi; Yue Xiu Pan; Jin Bo Shen; Jun Ge Zhi; Yu Ping Dong

doi:10.1007/s10118-010-9014-0

Stability and electrochemical properties of full-conjugated self-assembled films based on polyaniline and its acid-substituted derivates

Miao Miao Xiao, Bin Tong, Wei Zhao, Jian Bing Shi, Yue Xiu Pan, Jin Bo Shen, Jun Ge Zhi, Yu Ping Dong^*

^*此作品的通讯作者

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

6 引用（Scopus）

摘要

The stability of full-conjugated self-assembled (SA) multilayer films based on partially doped polyaniline (PANI) as a polycation and poly(o-aminobenzoic acid) (PCAN), poly(aniline-2-sulfonic acid) (PSAN) as polyanions is investigated in alkali aqueous solutions. The self-assembled PANI-PCAN films keep their stability within 24 h in 1 mol/L NaOH solution, -the PANI-PSAN films, however, maintain the stability for 20 min in the same condition because the solubility of PSAN in alkali solutions is much higher than that of PCAN. The electrochemical properties of the SA films are determined, and the film-CdS composites formed in situ are also reported.

源语言	英语
页（从-至）	331-336
页数	6
期刊	Chinese Journal of Polymer Science (English Edition)
卷	28
期	3
DOI	https://doi.org/10.1007/s10118-010-9014-0
出版状态	已出版 - 5月 2010

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title = "Stability and electrochemical properties of full-conjugated self-assembled films based on polyaniline and its acid-substituted derivates",

abstract = "The stability of full-conjugated self-assembled (SA) multilayer films based on partially doped polyaniline (PANI) as a polycation and poly(o-aminobenzoic acid) (PCAN), poly(aniline-2-sulfonic acid) (PSAN) as polyanions is investigated in alkali aqueous solutions. The self-assembled PANI-PCAN films keep their stability within 24 h in 1 mol/L NaOH solution, -the PANI-PSAN films, however, maintain the stability for 20 min in the same condition because the solubility of PSAN in alkali solutions is much higher than that of PCAN. The electrochemical properties of the SA films are determined, and the film-CdS composites formed in situ are also reported.",

keywords = "Electrochemical Properties, Film-CdS composites, Polyanilines, Self-assembly multilayer films",

author = "Xiao, {Miao Miao} and Bin Tong and Wei Zhao and Shi, {Jian Bing} and Pan, {Yue Xiu} and Shen, {Jin Bo} and Zhi, {Jun Ge} and Dong, {Yu Ping}",

year = "2010",

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doi = "10.1007/s10118-010-9014-0",

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T1 - Stability and electrochemical properties of full-conjugated self-assembled films based on polyaniline and its acid-substituted derivates

AU - Xiao, Miao Miao

AU - Tong, Bin

AU - Zhao, Wei

AU - Shi, Jian Bing

AU - Pan, Yue Xiu

AU - Shen, Jin Bo

AU - Zhi, Jun Ge

AU - Dong, Yu Ping

PY - 2010/5

Y1 - 2010/5

N2 - The stability of full-conjugated self-assembled (SA) multilayer films based on partially doped polyaniline (PANI) as a polycation and poly(o-aminobenzoic acid) (PCAN), poly(aniline-2-sulfonic acid) (PSAN) as polyanions is investigated in alkali aqueous solutions. The self-assembled PANI-PCAN films keep their stability within 24 h in 1 mol/L NaOH solution, -the PANI-PSAN films, however, maintain the stability for 20 min in the same condition because the solubility of PSAN in alkali solutions is much higher than that of PCAN. The electrochemical properties of the SA films are determined, and the film-CdS composites formed in situ are also reported.

AB - The stability of full-conjugated self-assembled (SA) multilayer films based on partially doped polyaniline (PANI) as a polycation and poly(o-aminobenzoic acid) (PCAN), poly(aniline-2-sulfonic acid) (PSAN) as polyanions is investigated in alkali aqueous solutions. The self-assembled PANI-PCAN films keep their stability within 24 h in 1 mol/L NaOH solution, -the PANI-PSAN films, however, maintain the stability for 20 min in the same condition because the solubility of PSAN in alkali solutions is much higher than that of PCAN. The electrochemical properties of the SA films are determined, and the film-CdS composites formed in situ are also reported.

KW - Electrochemical Properties

KW - Film-CdS composites

KW - Polyanilines

KW - Self-assembly multilayer films

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U2 - 10.1007/s10118-010-9014-0

DO - 10.1007/s10118-010-9014-0

M3 - Article

AN - SCOPUS:77954063743

SN - 0256-7679

VL - 28

SP - 331

EP - 336

JO - Chinese Journal of Polymer Science (English Edition)

JF - Chinese Journal of Polymer Science (English Edition)

IS - 3

ER -

Stability and electrochemical properties of full-conjugated self-assembled films based on polyaniline and its acid-substituted derivates

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