Spin crossover of a dinuclear Fe(II) complex in the trans-isomeric structure

Ya Nan Dong, Jin Peng Xue, Meng Yu*, Jun Tao

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

4 引用 (Scopus)

摘要

A trans-isomeric dinuclear complex is synthesized by reacting ligand 4-((1H-pyrrol-2-yl)methylene-amino)-4H-1,2,4-triazole (pyrtrz) with [Fe(NCS)2] in methanol, i.e. trans-[Fe2(pyrtrz)5(NCS)4]·7MeOH (trans-1·7MeOH), which shows complete spin-crossover behaviour from the structural point of view and incomplete spin crossover due to the partial loss of guest solvent molecules.

源语言英语
文章编号109475
期刊Inorganic Chemistry Communications
140
DOI
出版状态已出版 - 6月 2022

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