Spin-crossover FeII4 squares: Two-step complete spin transition and reversible single-crystal-to-single-crystal transformation

Rong Jia Wei*, Qian Huo, Jun Tao, Rong Bin Huang, Lan Sun Zheng

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

128 引用 (Scopus)

摘要

High or low? A square FeII4 compound exhibits complete thermally and optically activated transition from four low-spin (LS) centers to four high-spin (HS) centers in two steps (see plot of magnetic susceptibility). Reversible desorption and resorption of guest water molecules causes a single-crystal-to-single-crystal transformation.

源语言英语
页(从-至)8940-8943
页数4
期刊Angewandte Chemie - International Edition
50
38
DOI
出版状态已出版 - 12 9月 2011
已对外发布

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