TY - JOUR
T1 - Solubilities of Dihydroxylammonium 5,5′-Bistetrazole-1,1′-diolate in Various Pure Solvents at Temperatures between 293.15 and 323.15 K
AU - Zhang, Chunyuan
AU - Jin, Shaohua
AU - Chen, Shusen
AU - Zhang, Yan
AU - Qin, Liang
AU - Wei, Xiaochun
AU - Shu, Qinghai
N1 - Publisher Copyright:
© 2016 American Chemical Society.
PY - 2016/5/12
Y1 - 2016/5/12
N2 - The solubility of newly insensitive energetic material dihydroxylammonium 5,5′-bis(tetrazole)-1,1′-diolate (TKX-50) was measured in ethyl acetate, ethanol, deionized water, dimethyl fumarate (DMF), formic acid, toluene, and dimethyl sulfoxide (DMSO) between 293.15 and 323.15 K at atmospheric pressure by the gravimetric method, which is increased with an increase of temperature. The order of the solubility is ethyl acetate < ethanol < toluene < deionized water < DMF < formic acid < DMSO. The experimental mole fraction solubility data were correlated with a simple Apleblat equation, showing a good fitting between the experimental data and Apleblat equation.
AB - The solubility of newly insensitive energetic material dihydroxylammonium 5,5′-bis(tetrazole)-1,1′-diolate (TKX-50) was measured in ethyl acetate, ethanol, deionized water, dimethyl fumarate (DMF), formic acid, toluene, and dimethyl sulfoxide (DMSO) between 293.15 and 323.15 K at atmospheric pressure by the gravimetric method, which is increased with an increase of temperature. The order of the solubility is ethyl acetate < ethanol < toluene < deionized water < DMF < formic acid < DMSO. The experimental mole fraction solubility data were correlated with a simple Apleblat equation, showing a good fitting between the experimental data and Apleblat equation.
UR - http://www.scopus.com/inward/record.url?scp=84971524834&partnerID=8YFLogxK
U2 - 10.1021/acs.jced.6b00009
DO - 10.1021/acs.jced.6b00009
M3 - Article
AN - SCOPUS:84971524834
SN - 0021-9568
VL - 61
SP - 1873
EP - 1875
JO - Journal of Chemical and Engineering Data
JF - Journal of Chemical and Engineering Data
IS - 5
ER -