Wang, Z., Jin, S., Li, L., Chao, H., Qian, S., Zhao, X., Sheng, X., Lu, Z., Gu, G., Chen, S., & Chen, K. (2023). Simulation of thermal hazards risk in octogen based on non-isothermal DSC data. Scientific Reports, 13(1), 文章 21191. https://doi.org/10.1038/s41598-023-48372-2
Wang, Zhi ; Jin, Shaohua ; Li, Lijie 等. / Simulation of thermal hazards risk in octogen based on non-isothermal DSC data. 在: Scientific Reports. 2023 ; 卷 13, 号码 1.
@article{7e55252598e246e68069ebced59853ec,
title = "Simulation of thermal hazards risk in octogen based on non-isothermal DSC data",
abstract = "To evaluate the possible thermal risks associated with the storage of octogen (HMX), non-isothermal differential scanning calorimetry (DSC) experiments were conducted in order to ascertain the kinetic model and parameters governing its thermal decomposition. DSC measurements indicate that HMX underwent a crystal transformation prior to thermal decomposition. A kinetic model for the autocatalytic thermal decomposition process was developed through the analysis of its primary exothermic peaks. Subsequently, numerical simulations were performed using the aforementioned kinetic model to assess the potential thermal explosion hazard of HMX under two distinct storage conditions. The comparison was made between the models of HMX autocatalytic decomposition temperature and thermal explosion critical temperature under two distinct storage conditions. The prediction of the influence of ambient temperature on the critical temperature of thermal explosion is conducted simultaneously. Finally, the thermal hazard parameters of HMX under different package quality are given.",
author = "Zhi Wang and Shaohua Jin and Lijie Li and Hui Chao and Shichuan Qian and Xinping Zhao and Xin Sheng and Zhiyan Lu and Guanghui Gu and Shusen Chen and Kun Chen",
note = "Publisher Copyright: {\textcopyright} 2023, The Author(s).",
year = "2023",
month = dec,
doi = "10.1038/s41598-023-48372-2",
language = "English",
volume = "13",
journal = "Scientific Reports",
issn = "2045-2322",
publisher = "Nature Publishing Group",
number = "1",
}
Wang, Z, Jin, S, Li, L, Chao, H, Qian, S, Zhao, X, Sheng, X, Lu, Z, Gu, G, Chen, S & Chen, K 2023, 'Simulation of thermal hazards risk in octogen based on non-isothermal DSC data', Scientific Reports, 卷 13, 号码 1, 21191. https://doi.org/10.1038/s41598-023-48372-2
Simulation of thermal hazards risk in octogen based on non-isothermal DSC data. / Wang, Zhi
; Jin, Shaohua; Li, Lijie 等.
在:
Scientific Reports, 卷 13, 号码 1, 21191, 12.2023.
科研成果: 期刊稿件 › 文章 › 同行评审
TY - JOUR
T1 - Simulation of thermal hazards risk in octogen based on non-isothermal DSC data
AU - Wang, Zhi
AU - Jin, Shaohua
AU - Li, Lijie
AU - Chao, Hui
AU - Qian, Shichuan
AU - Zhao, Xinping
AU - Sheng, Xin
AU - Lu, Zhiyan
AU - Gu, Guanghui
AU - Chen, Shusen
AU - Chen, Kun
N1 - Publisher Copyright:
© 2023, The Author(s).
PY - 2023/12
Y1 - 2023/12
N2 - To evaluate the possible thermal risks associated with the storage of octogen (HMX), non-isothermal differential scanning calorimetry (DSC) experiments were conducted in order to ascertain the kinetic model and parameters governing its thermal decomposition. DSC measurements indicate that HMX underwent a crystal transformation prior to thermal decomposition. A kinetic model for the autocatalytic thermal decomposition process was developed through the analysis of its primary exothermic peaks. Subsequently, numerical simulations were performed using the aforementioned kinetic model to assess the potential thermal explosion hazard of HMX under two distinct storage conditions. The comparison was made between the models of HMX autocatalytic decomposition temperature and thermal explosion critical temperature under two distinct storage conditions. The prediction of the influence of ambient temperature on the critical temperature of thermal explosion is conducted simultaneously. Finally, the thermal hazard parameters of HMX under different package quality are given.
AB - To evaluate the possible thermal risks associated with the storage of octogen (HMX), non-isothermal differential scanning calorimetry (DSC) experiments were conducted in order to ascertain the kinetic model and parameters governing its thermal decomposition. DSC measurements indicate that HMX underwent a crystal transformation prior to thermal decomposition. A kinetic model for the autocatalytic thermal decomposition process was developed through the analysis of its primary exothermic peaks. Subsequently, numerical simulations were performed using the aforementioned kinetic model to assess the potential thermal explosion hazard of HMX under two distinct storage conditions. The comparison was made between the models of HMX autocatalytic decomposition temperature and thermal explosion critical temperature under two distinct storage conditions. The prediction of the influence of ambient temperature on the critical temperature of thermal explosion is conducted simultaneously. Finally, the thermal hazard parameters of HMX under different package quality are given.
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U2 - 10.1038/s41598-023-48372-2
DO - 10.1038/s41598-023-48372-2
M3 - Article
C2 - 38040954
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SN - 2045-2322
VL - 13
JO - Scientific Reports
JF - Scientific Reports
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Wang Z, Jin S, Li L, Chao H, Qian S, Zhao X 等. Simulation of thermal hazards risk in octogen based on non-isothermal DSC data. Scientific Reports. 2023 12月;13(1):21191. doi: 10.1038/s41598-023-48372-2