Selective bromination of pyrrole derivatives, carbazole and aromatic amines with DMSO/HBr under mild conditions

Cong Liu; Rongji Dai; Guowei Yao; Yulin Deng

doi:10.3184/174751914X14114780483352

Selective bromination of pyrrole derivatives, carbazole and aromatic amines with DMSO/HBr under mild conditions

Cong Liu, Rongji Dai^*, Guowei Yao, Yulin Deng

^*此作品的通讯作者

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

44 引用（Scopus）

摘要

Bromination of pyrrole derivatives, carbazole and aromatic amines using the DMSO/HBr system affords high yields of the corresponding bromo compounds. Temperature control used in the bromination of anilines helped to promote selective formation of mono- or di-brominated products. Simple operation, low toxicity and high selectivity make this a promising new procedure for the bromination of aromatic compounds.

源语言	英语
页（从-至）	593-596
页数	4
期刊	Journal of Chemical Research
卷	38
期	10
DOI	https://doi.org/10.3184/174751914X14114780483352
出版状态	已出版 - 1 10月 2014

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Liu, C., Dai, R., Yao, G., & Deng, Y. (2014). Selective bromination of pyrrole derivatives, carbazole and aromatic amines with DMSO/HBr under mild conditions. Journal of Chemical Research, 38(10), 593-596. https://doi.org/10.3184/174751914X14114780483352

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abstract = "Bromination of pyrrole derivatives, carbazole and aromatic amines using the DMSO/HBr system affords high yields of the corresponding bromo compounds. Temperature control used in the bromination of anilines helped to promote selective formation of mono- or di-brominated products. Simple operation, low toxicity and high selectivity make this a promising new procedure for the bromination of aromatic compounds.",

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AU - Yao, Guowei

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AB - Bromination of pyrrole derivatives, carbazole and aromatic amines using the DMSO/HBr system affords high yields of the corresponding bromo compounds. Temperature control used in the bromination of anilines helped to promote selective formation of mono- or di-brominated products. Simple operation, low toxicity and high selectivity make this a promising new procedure for the bromination of aromatic compounds.

KW - Aromatic amines

KW - Bromination

KW - Bromodimethylsulfonium bromide

KW - DMSO/HBr

KW - Temperature control

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Selective bromination of pyrrole derivatives, carbazole and aromatic amines with DMSO/HBr under mild conditions

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