SbF5/PAF - A novel fluorinating reagent in preparing fluorine compounds

Heng Dao Quan*, Hui e. Yang, Masanori Tamura, Akira Sekiya

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

11 引用 (Scopus)

摘要

A novel fluorination reagent and catalyst, SbF5/PAF (porous aluminum fluoride), was prepared by impregnating SbCl5 into PAF and then treating with anhydrous hydrogen fluoride. The prepared reagent had an excellent catalytic activity in halogen-exchange, and also improved the properties of SbF5, such as hydroscopicity, corrosion, and toxicity. SbF5/PAF was successfully used in organic synthesis as a fluorinating reagent, and a fixed bed catalyst for F/Cl exchange.

源语言英语
页(从-至)1169-1172
页数4
期刊Journal of Fluorine Chemistry
125
7
DOI
出版状态已出版 - 7月 2004
已对外发布

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