Ru(N^N)3-Metalloligand Pillared Zr6-Organic Layers for Aerobic Photooxidation

Xiao Mei Wei; Yong Fang Qi; Sheng Li Huang; Guo Yu Yang

doi:10.1002/ejic.202200204

Ru(N^N)₃-Metalloligand Pillared Zr₆-Organic Layers for Aerobic Photooxidation

Xiao Mei Wei, Yong Fang Qi, Sheng Li Huang^*, Guo Yu Yang^*

^*此作品的通讯作者

化学与化工学院

科研成果: 期刊稿件 › 文章 › 同行评审

3 引用（Scopus）

摘要

The stable Zr₆-based coordination framework Ru-1 was assembled via the linkage of Zr₆-organic layers and photosensitized Ru(N^N)₃-metalloligand. Based on its 1D open channel and the incorporation of Ru(N^N)₃-photosensitizer, it can serve as a highly efficient heterogeneous catalyst in the aerobic photooxidation reactions, including photooxidation of sulfides, coupling of amines and oxidative hydroxylation of arylboronic acids. The stability and catalytic performance of recycled Ru-1 was also explored.

源语言	英语
文章编号	e202200204
期刊	European Journal of Inorganic Chemistry
卷	2022
期	20
DOI	https://doi.org/10.1002/ejic.202200204
出版状态	已出版 - 19 7月 2022

访问文件

10.1002/ejic.202200204

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{d18660ba93c94f67b795d9a78ffb5364,

title = "Ru(N^N)3-Metalloligand Pillared Zr6-Organic Layers for Aerobic Photooxidation",

abstract = "The stable Zr6-based coordination framework Ru-1 was assembled via the linkage of Zr6-organic layers and photosensitized Ru(N^N)3-metalloligand. Based on its 1D open channel and the incorporation of Ru(N^N)3-photosensitizer, it can serve as a highly efficient heterogeneous catalyst in the aerobic photooxidation reactions, including photooxidation of sulfides, coupling of amines and oxidative hydroxylation of arylboronic acids. The stability and catalytic performance of recycled Ru-1 was also explored.",

keywords = "Photocatalysis, Photooxidation, Reactive oxygen species, Ru(N^N)-metalloligand, Ru-photosensitizer",

author = "Wei, {Xiao Mei} and Qi, {Yong Fang} and Huang, {Sheng Li} and Yang, {Guo Yu}",

note = "Publisher Copyright: {\textcopyright} 2022 Wiley-VCH GmbH.",

year = "2022",

month = jul,

day = "19",

doi = "10.1002/ejic.202200204",

language = "English",

volume = "2022",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

number = "20",

}

TY - JOUR

T1 - Ru(N^N)3-Metalloligand Pillared Zr6-Organic Layers for Aerobic Photooxidation

AU - Wei, Xiao Mei

AU - Qi, Yong Fang

AU - Huang, Sheng Li

AU - Yang, Guo Yu

PY - 2022/7/19

Y1 - 2022/7/19

N2 - The stable Zr6-based coordination framework Ru-1 was assembled via the linkage of Zr6-organic layers and photosensitized Ru(N^N)3-metalloligand. Based on its 1D open channel and the incorporation of Ru(N^N)3-photosensitizer, it can serve as a highly efficient heterogeneous catalyst in the aerobic photooxidation reactions, including photooxidation of sulfides, coupling of amines and oxidative hydroxylation of arylboronic acids. The stability and catalytic performance of recycled Ru-1 was also explored.

AB - The stable Zr6-based coordination framework Ru-1 was assembled via the linkage of Zr6-organic layers and photosensitized Ru(N^N)3-metalloligand. Based on its 1D open channel and the incorporation of Ru(N^N)3-photosensitizer, it can serve as a highly efficient heterogeneous catalyst in the aerobic photooxidation reactions, including photooxidation of sulfides, coupling of amines and oxidative hydroxylation of arylboronic acids. The stability and catalytic performance of recycled Ru-1 was also explored.

KW - Photocatalysis

KW - Photooxidation

KW - Reactive oxygen species

KW - Ru(N^N)-metalloligand

KW - Ru-photosensitizer

UR - http://www.scopus.com/inward/record.url?scp=85131305648&partnerID=8YFLogxK

U2 - 10.1002/ejic.202200204

DO - 10.1002/ejic.202200204

M3 - Article

AN - SCOPUS:85131305648

SN - 1434-1948

VL - 2022

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 20

M1 - e202200204

ER -

Ru(N^N)3-Metalloligand Pillared Zr6-Organic Layers for Aerobic Photooxidation

摘要

访问文件

其它文件与链接

指纹

引用此

Ru(N^N)₃-Metalloligand Pillared Zr₆-Organic Layers for Aerobic Photooxidation