Rh nanoparticles catalyzed hydroformylation of olefins in a thermoregulated ionic liquid/organic biphasic system

Yan Zeng; Yanhua Wang; Yicheng Xu; Ying Song; Jiaqi Zhao; Jingyang Jiang; Zilin Jin

doi:10.1016/S1872-2067(11)60371-9

Rh nanoparticles catalyzed hydroformylation of olefins in a thermoregulated ionic liquid/organic biphasic system

Yan Zeng, Yanhua Wang^*, Yicheng Xu, Ying Song, Jiaqi Zhao, Jingyang Jiang, Zilin Jin

^*此作品的通讯作者

Dalian University of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

24 引用（Scopus）

摘要

Rh nanoparticles were investigated as a catalyst for hydroformylation of olefins in thermoregulated ionic liquid/organic biphasic systems composed of an ionic liquid, namely [CH₃(OCH₂CH₂) ₁₆N⁺Et₃][CH₃SO₃ ^-] (IL_PEG750), and an organic solvent. This enables not only a homogeneous reaction but also easy biphasic separation. Under the optimized reaction conditions, the conversion of 1-octene and yield of aldehyde were 99 and 91, respectively. The catalyst was easily separated from the product by phase separation and used eight times without evident loss of activity.

源语言	英语
页（从-至）	402-406
页数	5
期刊	Chinese Journal of Catalysis
卷	33
期	2-3
DOI	https://doi.org/10.1016/S1872-2067(11)60371-9
出版状态	已出版 - 2012
已对外发布	是

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title = "Rh nanoparticles catalyzed hydroformylation of olefins in a thermoregulated ionic liquid/organic biphasic system",

abstract = "Rh nanoparticles were investigated as a catalyst for hydroformylation of olefins in thermoregulated ionic liquid/organic biphasic systems composed of an ionic liquid, namely [CH3(OCH2CH2) 16N+Et3][CH3SO3 -] (ILPEG750), and an organic solvent. This enables not only a homogeneous reaction but also easy biphasic separation. Under the optimized reaction conditions, the conversion of 1-octene and yield of aldehyde were 99 and 91, respectively. The catalyst was easily separated from the product by phase separation and used eight times without evident loss of activity.",

keywords = "hydroformylation, nanoparticle, olefin, rhodium, thermoregulated ionic liquid/organic biphasic system",

author = "Yan Zeng and Yanhua Wang and Yicheng Xu and Ying Song and Jiaqi Zhao and Jingyang Jiang and Zilin Jin",

year = "2012",

doi = "10.1016/S1872-2067(11)60371-9",

language = "English",

volume = "33",

pages = "402--406",

journal = "Chinese Journal of Catalysis",

issn = "1872-2067",

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TY - JOUR

T1 - Rh nanoparticles catalyzed hydroformylation of olefins in a thermoregulated ionic liquid/organic biphasic system

AU - Zeng, Yan

AU - Wang, Yanhua

AU - Xu, Yicheng

AU - Song, Ying

AU - Zhao, Jiaqi

AU - Jiang, Jingyang

AU - Jin, Zilin

PY - 2012

Y1 - 2012

N2 - Rh nanoparticles were investigated as a catalyst for hydroformylation of olefins in thermoregulated ionic liquid/organic biphasic systems composed of an ionic liquid, namely [CH3(OCH2CH2) 16N+Et3][CH3SO3 -] (ILPEG750), and an organic solvent. This enables not only a homogeneous reaction but also easy biphasic separation. Under the optimized reaction conditions, the conversion of 1-octene and yield of aldehyde were 99 and 91, respectively. The catalyst was easily separated from the product by phase separation and used eight times without evident loss of activity.

AB - Rh nanoparticles were investigated as a catalyst for hydroformylation of olefins in thermoregulated ionic liquid/organic biphasic systems composed of an ionic liquid, namely [CH3(OCH2CH2) 16N+Et3][CH3SO3 -] (ILPEG750), and an organic solvent. This enables not only a homogeneous reaction but also easy biphasic separation. Under the optimized reaction conditions, the conversion of 1-octene and yield of aldehyde were 99 and 91, respectively. The catalyst was easily separated from the product by phase separation and used eight times without evident loss of activity.

KW - hydroformylation

KW - nanoparticle

KW - olefin

KW - rhodium

KW - thermoregulated ionic liquid/organic biphasic system

UR - http://www.scopus.com/inward/record.url?scp=84859782226&partnerID=8YFLogxK

U2 - 10.1016/S1872-2067(11)60371-9

DO - 10.1016/S1872-2067(11)60371-9

M3 - Article

AN - SCOPUS:84859782226

SN - 1872-2067

VL - 33

SP - 402

EP - 406

JO - Chinese Journal of Catalysis

JF - Chinese Journal of Catalysis

IS - 2-3

ER -

Rh nanoparticles catalyzed hydroformylation of olefins in a thermoregulated ionic liquid/organic biphasic system

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