Responsive gels with the polymer containing alternating naphthalene diimide and fluorinated alkyl chains: Gel formation and responsiveness as well as electrical conductivity of polymer thin films

Hewei Luo; Zitong Liu; Zhengxu Cai; Liusuo Wu; Guanxin Zhang; Chenyang Liu; Deqing Zhang

doi:10.1002/cjoc.201200029

Responsive gels with the polymer containing alternating naphthalene diimide and fluorinated alkyl chains: Gel formation and responsiveness as well as electrical conductivity of polymer thin films

Hewei Luo^*, Zitong Liu, Zhengxu Cai, Liusuo Wu, Guanxin Zhang, Chenyang Liu, Deqing Zhang

^*此作品的通讯作者

CAS - Institute of Chemistry

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8 引用（Scopus）

摘要

A new electroactive polymer 1 with alternating NDI (naphthalene diimide) moieties and fluorinated alkyl chains was prepared and characterized. Gels of polymer 1 were formed in several solvents. Interestingly, gels of polymer 1 exhibited responsiveness toward N ₂H ₄, F ^- and CN ^-. Absorption and ESR spectroscopic studies revealed that such responsiveness is owing to the reduction of NDI moieties into the respective NDI ^.-. In addition, thin films of polymer 1 were easily prepared with spin-coating technique and the electrical conductivity of thin films reached 52.4 S/m after exposure to N ₂H ₄ vapor.

源语言	英语
页（从-至）	1453-1458
页数	6
期刊	Chinese Journal of Chemistry
卷	30
期	7
DOI	https://doi.org/10.1002/cjoc.201200029
出版状态	已出版 - 7月 2012
已对外发布	是

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Luo, H., Liu, Z., Cai, Z., Wu, L., Zhang, G., Liu, C., & Zhang, D. (2012). Responsive gels with the polymer containing alternating naphthalene diimide and fluorinated alkyl chains: Gel formation and responsiveness as well as electrical conductivity of polymer thin films. Chinese Journal of Chemistry, 30(7), 1453-1458. https://doi.org/10.1002/cjoc.201200029

@article{7b7ca602565547b18fe7a14cdfbae3bd,

title = "Responsive gels with the polymer containing alternating naphthalene diimide and fluorinated alkyl chains: Gel formation and responsiveness as well as electrical conductivity of polymer thin films",

abstract = "A new electroactive polymer 1 with alternating NDI (naphthalene diimide) moieties and fluorinated alkyl chains was prepared and characterized. Gels of polymer 1 were formed in several solvents. Interestingly, gels of polymer 1 exhibited responsiveness toward N 2H 4, F - and CN -. Absorption and ESR spectroscopic studies revealed that such responsiveness is owing to the reduction of NDI moieties into the respective NDI .-. In addition, thin films of polymer 1 were easily prepared with spin-coating technique and the electrical conductivity of thin films reached 52.4 S/m after exposure to N 2H 4 vapor.",

keywords = "electrical conductivity, electroactive polymer, naphthalene diimide, radical anion of naphthalene diimide, responsive gels",

author = "Hewei Luo and Zitong Liu and Zhengxu Cai and Liusuo Wu and Guanxin Zhang and Chenyang Liu and Deqing Zhang",

year = "2012",

month = jul,

doi = "10.1002/cjoc.201200029",

language = "English",

volume = "30",

pages = "1453--1458",

journal = "Chinese Journal of Chemistry",

issn = "1001-604X",

publisher = "John Wiley and Sons Inc.",

number = "7",

}

Responsive gels with the polymer containing alternating naphthalene diimide and fluorinated alkyl chains: Gel formation and responsiveness as well as electrical conductivity of polymer thin films. / Luo, Hewei; Liu, Zitong; Cai, Zhengxu 等.
在: Chinese Journal of Chemistry, 卷 30, 号码 7, 07.2012, 页码 1453-1458.

科研成果: 期刊稿件 › 文章 › 同行评审

TY - JOUR

T1 - Responsive gels with the polymer containing alternating naphthalene diimide and fluorinated alkyl chains

T2 - Gel formation and responsiveness as well as electrical conductivity of polymer thin films

AU - Luo, Hewei

AU - Liu, Zitong

AU - Cai, Zhengxu

AU - Wu, Liusuo

AU - Zhang, Guanxin

AU - Liu, Chenyang

AU - Zhang, Deqing

PY - 2012/7

Y1 - 2012/7

N2 - A new electroactive polymer 1 with alternating NDI (naphthalene diimide) moieties and fluorinated alkyl chains was prepared and characterized. Gels of polymer 1 were formed in several solvents. Interestingly, gels of polymer 1 exhibited responsiveness toward N 2H 4, F - and CN -. Absorption and ESR spectroscopic studies revealed that such responsiveness is owing to the reduction of NDI moieties into the respective NDI .-. In addition, thin films of polymer 1 were easily prepared with spin-coating technique and the electrical conductivity of thin films reached 52.4 S/m after exposure to N 2H 4 vapor.

AB - A new electroactive polymer 1 with alternating NDI (naphthalene diimide) moieties and fluorinated alkyl chains was prepared and characterized. Gels of polymer 1 were formed in several solvents. Interestingly, gels of polymer 1 exhibited responsiveness toward N 2H 4, F - and CN -. Absorption and ESR spectroscopic studies revealed that such responsiveness is owing to the reduction of NDI moieties into the respective NDI .-. In addition, thin films of polymer 1 were easily prepared with spin-coating technique and the electrical conductivity of thin films reached 52.4 S/m after exposure to N 2H 4 vapor.

KW - electrical conductivity

KW - electroactive polymer

KW - naphthalene diimide

KW - radical anion of naphthalene diimide

KW - responsive gels

UR - http://www.scopus.com/inward/record.url?scp=84864138869&partnerID=8YFLogxK

U2 - 10.1002/cjoc.201200029

DO - 10.1002/cjoc.201200029

M3 - Article

AN - SCOPUS:84864138869

SN - 1001-604X

VL - 30

SP - 1453

EP - 1458

JO - Chinese Journal of Chemistry

JF - Chinese Journal of Chemistry

IS - 7

ER -

Responsive gels with the polymer containing alternating naphthalene diimide and fluorinated alkyl chains: Gel formation and responsiveness as well as electrical conductivity of polymer thin films

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