Regulating Spin-State Switching by Integrating Polyoxometalate Anion into Spin Crossover System

Jiajia Li, Xiao Peng Sun*, Shiqi Bi, Minglu Xu, Siyu Jia, Zheng Tang, Pengtao Ma, Jingping Wang, Jun Tao, Jingyang Niu*

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

8 引用 (Scopus)

摘要

Polyoxometalate (POM) anions were successfully integrated into Fe(II) spin crossover (SCO) system, which demonstrates an effective role in regulating spin-state switching properties. Specifically, three drastically different magnetic behaviors of Fe(II) ion in the identical cation [Fe(bpp)2]2+were achieved by leveraging [Mo6O19]2-, [Mo8O26]4-, and [Na(Mo8O26)]3-, respectively.

源语言英语
页(从-至)17932-17936
页数5
期刊Inorganic Chemistry
61
45
DOI
出版状态已出版 - 14 11月 2022

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