@article{a2f66a6f68a04802a92d6afca066b51d,
title = "Reductive linear- and cyclo-trimerization of isocyanides using an Al-Al-bonded compound",
abstract = "Dialumane 1 reacts with tBuNC to produce a reductive dimerization adduct [LAl(tBuNC-CNtBu)AlL] (2). In the presence of Na, 1 can promote linear- and cyclo-trimerization of isocyanides, affording products [Na][LAl{(tBuNC)3}AlL] (3 and 4) and [Na][LAl{(tBuNC)3}Al(CN)L] (5), the latter of which features a unique aromatic tri(tert-butylimino)deltate dianion [C3N3(tBu)3]2-.",
author = "Weixing Chen and Yanxia Zhao and Wenhua Xu and Su, {Ji Hu} and Lingyi Shen and Li Liu and Biao Wu and Yang, {Xiao Juan}",
note = "Publisher Copyright: {\textcopyright} 2019 The Royal Society of Chemistry.",
year = "2019",
doi = "10.1039/c9cc04344f",
language = "English",
volume = "55",
pages = "9452--9455",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "64",
}