Reaction of frustrated lewis pairs with conjugated ynones-selective hydrogenation of the carbon-carbon triple bond

Bao Hua Xu, Gerald Kehr, Roland Fröhlich, Birgit Wibbeling, Birgitta Schirmer, Stefan Grimme, Gerhard Erker*

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

168 引用 (Scopus)

摘要

Frustrated, but not frustrating: Frustrated Lewis pairs (FLPs) can undergo selective 1,4-addition reactions with conjugated ynones (see scheme). Upon FLP dihydrogen activation selective hydrogenation of the carbon-carbon triple bond can be achieved, in one case even catalytically.

源语言英语
页(从-至)7183-7186
页数4
期刊Angewandte Chemie - International Edition
50
31
DOI
出版状态已出版 - 25 7月 2011
已对外发布

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