TY - JOUR
T1 - Reaction of 2-methylnaphthalene with hexachlorocyclopentadiene and structural characterization of a new addition-substitution product
AU - Du, Da Ming
AU - Xue, Feng
AU - Wong, Henry N.C.
AU - Mak, Thomas C.W.
PY - 1998/11
Y1 - 1998/11
N2 - 2-Methylnaphthalene undergoes Diels-Alder addition and substitution with hexachlorocyclopentadiene to give two products, 1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-10- methyl-1,4;5,8-dimethanotriphenylene 1 and 1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-10- (1′,2′,3′,4′,5′-pentachlorocyclopentadienyl) methyl-1, 4;5,8-dimethanotriphenylene 2. The molecular structure of 2 has been characterized by X-ray crystallography: C26H9Cl17, monoclinic, space group P21/c, with a = 15.316(3), b = 13.698(3), c = 16.116(3) Å, β = 96.113(3)°, and Z = 4.
AB - 2-Methylnaphthalene undergoes Diels-Alder addition and substitution with hexachlorocyclopentadiene to give two products, 1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-10- methyl-1,4;5,8-dimethanotriphenylene 1 and 1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-10- (1′,2′,3′,4′,5′-pentachlorocyclopentadienyl) methyl-1, 4;5,8-dimethanotriphenylene 2. The molecular structure of 2 has been characterized by X-ray crystallography: C26H9Cl17, monoclinic, space group P21/c, with a = 15.316(3), b = 13.698(3), c = 16.116(3) Å, β = 96.113(3)°, and Z = 4.
KW - 2-Methylnaphthalene
KW - Crystal structure
KW - Hexachlorocyclopentadiene
UR - http://www.scopus.com/inward/record.url?scp=0032244806&partnerID=8YFLogxK
U2 - 10.1023/A:1021819518557
DO - 10.1023/A:1021819518557
M3 - Article
AN - SCOPUS:0032244806
SN - 1074-1542
VL - 28
SP - 787
EP - 790
JO - Journal of Chemical Crystallography
JF - Journal of Chemical Crystallography
IS - 11
ER -