Reaction of 2-methylnaphthalene with hexachlorocyclopentadiene and structural characterization of a new addition-substitution product

Da Ming Du; Feng Xue; Henry N.C. Wong; Thomas C.W. Mak

doi:10.1023/A:1021819518557

Reaction of 2-methylnaphthalene with hexachlorocyclopentadiene and structural characterization of a new addition-substitution product

Da Ming Du, Feng Xue, Henry N.C. Wong^*, Thomas C.W. Mak

^*此作品的通讯作者

科研成果: 期刊稿件 › 文章 › 同行评审

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2-Methylnaphthalene undergoes Diels-Alder addition and substitution with hexachlorocyclopentadiene to give two products, 1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-10- methyl-1,4;5,8-dimethanotriphenylene 1 and 1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-10- (1′,2′,3′,4′,5′-pentachlorocyclopentadienyl) methyl-1, 4;5,8-dimethanotriphenylene 2. The molecular structure of 2 has been characterized by X-ray crystallography: C₂₆H₉Cl₁₇, monoclinic, space group P2₁/c, with a = 15.316(3), b = 13.698(3), c = 16.116(3) Å, β = 96.113(3)°, and Z = 4.

源语言	英语
页（从-至）	787-790
页数	4
期刊	Journal of Chemical Crystallography
卷	28
期	11
DOI	https://doi.org/10.1023/A:1021819518557
出版状态	已出版 - 11月 1998
已对外发布	是

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Du, D. M., Xue, F., Wong, H. N. C., & Mak, T. C. W. (1998). Reaction of 2-methylnaphthalene with hexachlorocyclopentadiene and structural characterization of a new addition-substitution product. Journal of Chemical Crystallography, 28(11), 787-790. https://doi.org/10.1023/A:1021819518557

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title = "Reaction of 2-methylnaphthalene with hexachlorocyclopentadiene and structural characterization of a new addition-substitution product",

abstract = "2-Methylnaphthalene undergoes Diels-Alder addition and substitution with hexachlorocyclopentadiene to give two products, 1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-10- methyl-1,4;5,8-dimethanotriphenylene 1 and 1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-10- (1′,2′,3′,4′,5′-pentachlorocyclopentadienyl) methyl-1, 4;5,8-dimethanotriphenylene 2. The molecular structure of 2 has been characterized by X-ray crystallography: C26H9Cl17, monoclinic, space group P21/c, with a = 15.316(3), b = 13.698(3), c = 16.116(3) {\AA}, β = 96.113(3)°, and Z = 4.",

keywords = "2-Methylnaphthalene, Crystal structure, Hexachlorocyclopentadiene",

author = "Du, {Da Ming} and Feng Xue and Wong, {Henry N.C.} and Mak, {Thomas C.W.}",

year = "1998",

month = nov,

doi = "10.1023/A:1021819518557",

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T1 - Reaction of 2-methylnaphthalene with hexachlorocyclopentadiene and structural characterization of a new addition-substitution product

AU - Du, Da Ming

AU - Xue, Feng

AU - Wong, Henry N.C.

AU - Mak, Thomas C.W.

PY - 1998/11

Y1 - 1998/11

N2 - 2-Methylnaphthalene undergoes Diels-Alder addition and substitution with hexachlorocyclopentadiene to give two products, 1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-10- methyl-1,4;5,8-dimethanotriphenylene 1 and 1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-10- (1′,2′,3′,4′,5′-pentachlorocyclopentadienyl) methyl-1, 4;5,8-dimethanotriphenylene 2. The molecular structure of 2 has been characterized by X-ray crystallography: C26H9Cl17, monoclinic, space group P21/c, with a = 15.316(3), b = 13.698(3), c = 16.116(3) Å, β = 96.113(3)°, and Z = 4.

AB - 2-Methylnaphthalene undergoes Diels-Alder addition and substitution with hexachlorocyclopentadiene to give two products, 1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-10- methyl-1,4;5,8-dimethanotriphenylene 1 and 1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-10- (1′,2′,3′,4′,5′-pentachlorocyclopentadienyl) methyl-1, 4;5,8-dimethanotriphenylene 2. The molecular structure of 2 has been characterized by X-ray crystallography: C26H9Cl17, monoclinic, space group P21/c, with a = 15.316(3), b = 13.698(3), c = 16.116(3) Å, β = 96.113(3)°, and Z = 4.

KW - 2-Methylnaphthalene

KW - Crystal structure

KW - Hexachlorocyclopentadiene

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U2 - 10.1023/A:1021819518557

DO - 10.1023/A:1021819518557

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JO - Journal of Chemical Crystallography

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Reaction of 2-methylnaphthalene with hexachlorocyclopentadiene and structural characterization of a new addition-substitution product

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