Providing A Long-Term Protection for NCM811 Cathode Material by Al2O3 Coating Layer

Jing Wang*, Qiang Yuan, Ran Wang, Guoqiang Tan, Yuefeng Su, Danhua Li, Feng Wu

*此作品的通讯作者

科研成果: 期刊稿件会议文章同行评审

7 引用 (Scopus)

摘要

The degradation of Ni-rich LiNi0.8Co0.1Mn0.1O2 cathode material is successfully suppressed via a facile Al2O3 coating method. The coated Al2O3 layer on the electrode surface is inactive and amorphous, it does not react with the electrolyte and could provide a long-Term protection on the electrode during cycling. The electrochemical performance of the modified NCM811 was improved dramatically both at room and elevated temperature. The capacity retention of pristine NCM811 was enhanced from 81.8% to 91.7% when the coating amount reached to 2 wt% at 25°C and much increased from 68.5% to 87.7% at 55°C. Such excellent high temperature performance clearly confirmed the effect of Al2O3 on the structure stability of electrode, it successfully built a favorable protection of the bulk NCM811 from direct contact with electrolyte and suppressed the undesired side reactions.

源语言英语
文章编号012007
期刊IOP Conference Series: Materials Science and Engineering
735
1
DOI
出版状态已出版 - 17 1月 2020
活动7th Annual International Conference on Material Science and Environmental Engineering, MSEE 2019 - Wuhan, Hubei, 中国
期限: 15 11月 201916 11月 2019

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