摘要
A three-dimensional mixed-valence iron complex with NiAs-type topology, [(FeIII3O)FeII(TA)6(H 2O)3]•(ClO4)2(NO 3)(EtOH)(H2O)2 (1, HTA = tetrazole-1H-acetic acid), shows spin-crossover behavior that was characterized via variable-temperature crystal structures, Mössbauer spectra and magnetic susceptibilities, the pressure effects on the transition behavior were also studied.
源语言 | 英语 |
---|---|
页(从-至) | 1753-1755 |
页数 | 3 |
期刊 | Chemical Communications |
期 | 15 |
DOI | |
出版状态 | 已出版 - 2008 |
已对外发布 | 是 |