Preparation of 1,1,1,2-tetrafluoroethane by the vapor-phase catalytic reaction of 1,1,1-trifluoro-2-chloroethane with anhydrous hydrogen fluoride

Heng Dao Quan, Hui e. Yang, Zhong Li, Jian Zhang Ren, Hui Li Li

科研成果: 期刊稿件文章同行评审

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摘要

1,1,1,2-Tetrafluoroethane was prepared in 97% selectivity by the vapor-phase catalytic reaction of 1,1,1-trifluoro-2-chloroethane with anhydrous hydrogen fluoride (AHF) over a metal fluoride catalyst (CrF3 and CoF2) supported on porous aluminum fluoride (PAF). The relationship between the crystalline phase transition of porous aluminum fluoride and temperature from 100 to 640°C was investigated by X-ray diffraction.

源语言英语
页(从-至)193-199
页数7
期刊Journal of Fluorine Chemistry
111
2
DOI
出版状态已出版 - 2001
已对外发布

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