Preparation and crystal structure of [Cu(TO)2(H 2O)4](PA)2

Jian Guo Zhang; Tong Lai Zhang; Li Yang; Li Qiu Mao; Kai Bei Yu

Preparation and crystal structure of [Cu(TO)₂(H ₂O)₄](PA)₂

Jian Guo Zhang^*, Tong Lai Zhang, Li Yang, Li Qiu Mao, Kai Bei Yu

^*此作品的通讯作者

机电学院

科研成果: 期刊稿件 › 文章 › 同行评审

8 引用（Scopus）

摘要

[Cu(TO)₂(H₂O)₄](PA)₂ was prepared by mixing the aqueous solution of 1, 2, 4-triazol-5-one(TO) and Cu(PA)₂. The molecular structure and crystal structure of the title complex was determined by X-ray single crystal diffraction method. The crystal is triclinic, space group with a = 0.7321(1) nm, b = 0.7474(2) nm, c = 1.3649 (3) nm; α = 88.65(2)°, β = 85.63(1)°, γ = 63.35(1)°; V = 0.6655(2) nm³, Z = 1. The Cu²⁺ coordinated with two TO molecule through its 2-nitrogen atom and four water molecules and showed an octahedral configuration.

源语言	英语
页（从-至）	284-288
页数	5
期刊	Chinese Journal of Inorganic Chemistry
卷	18
期	3
出版状态	已出版 - 2002

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引用此

@article{afaeaf328df5463bb9e3ab86055b7915,

title = "Preparation and crystal structure of [Cu(TO)2(H 2O)4](PA)2 ",

abstract = "[Cu(TO)2(H2O)4](PA)2 was prepared by mixing the aqueous solution of 1, 2, 4-triazol-5-one(TO) and Cu(PA)2. The molecular structure and crystal structure of the title complex was determined by X-ray single crystal diffraction method. The crystal is triclinic, space group with a = 0.7321(1) nm, b = 0.7474(2) nm, c = 1.3649 (3) nm; α = 88.65(2)°, β = 85.63(1)°, γ = 63.35(1)°; V = 0.6655(2) nm3, Z = 1. The Cu2+ coordinated with two TO molecule through its 2-nitrogen atom and four water molecules and showed an octahedral configuration.",

keywords = "1,2,4-triazol-5-one(TO), Copper complex, Crystal structure, Preparation",

author = "Zhang, {Jian Guo} and Zhang, {Tong Lai} and Li Yang and Mao, {Li Qiu} and Yu, {Kai Bei}",

year = "2002",

language = "English",

volume = "18",

pages = "284--288",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

number = "3",

}

TY - JOUR

T1 - Preparation and crystal structure of [Cu(TO)2(H 2O)4](PA)2

AU - Zhang, Jian Guo

AU - Zhang, Tong Lai

AU - Yang, Li

AU - Mao, Li Qiu

AU - Yu, Kai Bei

PY - 2002

Y1 - 2002

N2 - [Cu(TO)2(H2O)4](PA)2 was prepared by mixing the aqueous solution of 1, 2, 4-triazol-5-one(TO) and Cu(PA)2. The molecular structure and crystal structure of the title complex was determined by X-ray single crystal diffraction method. The crystal is triclinic, space group with a = 0.7321(1) nm, b = 0.7474(2) nm, c = 1.3649 (3) nm; α = 88.65(2)°, β = 85.63(1)°, γ = 63.35(1)°; V = 0.6655(2) nm3, Z = 1. The Cu2+ coordinated with two TO molecule through its 2-nitrogen atom and four water molecules and showed an octahedral configuration.

AB - [Cu(TO)2(H2O)4](PA)2 was prepared by mixing the aqueous solution of 1, 2, 4-triazol-5-one(TO) and Cu(PA)2. The molecular structure and crystal structure of the title complex was determined by X-ray single crystal diffraction method. The crystal is triclinic, space group with a = 0.7321(1) nm, b = 0.7474(2) nm, c = 1.3649 (3) nm; α = 88.65(2)°, β = 85.63(1)°, γ = 63.35(1)°; V = 0.6655(2) nm3, Z = 1. The Cu2+ coordinated with two TO molecule through its 2-nitrogen atom and four water molecules and showed an octahedral configuration.

KW - 1,2,4-triazol-5-one(TO)

KW - Copper complex

KW - Crystal structure

KW - Preparation

UR - http://www.scopus.com/inward/record.url?scp=23044532617&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:23044532617

SN - 1001-4861

VL - 18

SP - 284

EP - 288

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 3

ER -

Preparation and crystal structure of [Cu(TO)2(H 2O)4](PA)2

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Preparation and crystal structure of [Cu(TO)₂(H ₂O)₄](PA)₂