TY - JOUR
T1 - Preparation and characterization of yellow waterborne polyurethane with 2,6-diaminoanthraquinone structure
AU - Zhao, Jia
AU - Hou, Jinghui
AU - Chai, Chunpeng
AU - Yang, Xuanhe
AU - Yao, Yanqing
N1 - Publisher Copyright:
© 2021 The Authors
PY - 2022/2
Y1 - 2022/2
N2 - Poly (2-methyl-1,3-propylene glycol-adipic acid) ester diol (PMA-1000), 2,2-dihydroxymethyl propionic acid (DMPA), toluene diisocyanate (TDI), 1,4-butanediol (BDO), 2,6-diaminoanthraquinone (DAAQ) were used as raw materials, triethylamine (TEA) as neutralizer, and yellow waterborne polyurethane dye (DAAQ-WPU) containing DAAQ was obtained after emulsification. The structure and properties of the product were characterized by infrared spectroscopy, fluorescence spectrophotometer, laser particle size analyzer, spectrophotometer and color fastness tester. The results show that, DAAQ anthraquinone structure is connected to the water-based polyurethane chain, DAAQ-WPU is synthesized, and its emulsion has purple fluorescence at 300–350 nm band. With the increase of DAAQ content, the particle size of DAAQ-WPU emulsion increases from 69.7 nm to 104.9 nm, the b* value of film increases from 10.4 to 45.39, and the yellow color deepens gradually. DAAQ-WPU has good color fastness to cotton cloth, and its color fastness to rubbing, water stain and soaping is 4–5 grade.
AB - Poly (2-methyl-1,3-propylene glycol-adipic acid) ester diol (PMA-1000), 2,2-dihydroxymethyl propionic acid (DMPA), toluene diisocyanate (TDI), 1,4-butanediol (BDO), 2,6-diaminoanthraquinone (DAAQ) were used as raw materials, triethylamine (TEA) as neutralizer, and yellow waterborne polyurethane dye (DAAQ-WPU) containing DAAQ was obtained after emulsification. The structure and properties of the product were characterized by infrared spectroscopy, fluorescence spectrophotometer, laser particle size analyzer, spectrophotometer and color fastness tester. The results show that, DAAQ anthraquinone structure is connected to the water-based polyurethane chain, DAAQ-WPU is synthesized, and its emulsion has purple fluorescence at 300–350 nm band. With the increase of DAAQ content, the particle size of DAAQ-WPU emulsion increases from 69.7 nm to 104.9 nm, the b* value of film increases from 10.4 to 45.39, and the yellow color deepens gradually. DAAQ-WPU has good color fastness to cotton cloth, and its color fastness to rubbing, water stain and soaping is 4–5 grade.
KW - 2,6-Diaminoanthraquinone structure
KW - Color fastness
KW - Dye
KW - Emulsion
KW - Waterborne polyurethane
UR - http://www.scopus.com/inward/record.url?scp=85121216730&partnerID=8YFLogxK
U2 - 10.1016/j.polymertesting.2021.107451
DO - 10.1016/j.polymertesting.2021.107451
M3 - Article
AN - SCOPUS:85121216730
SN - 0142-9418
VL - 106
JO - Polymer Testing
JF - Polymer Testing
M1 - 107451
ER -
