Gao, X., Zhang, H., Guan, J., Shi, D., Wu, Q., Chen, K. C., Zhang, Y., Feng, C., Zhao, Y., Jiao, Q., & Li, H. (2021). Pomegranate-like Core-Shell Ni-NSs@MSNSs as a High Activity, Good Stability, Rapid Magnetic Separation, and Multiple Recyclability Nanocatalyst for DCPD Hydrogenation. ACS Omega, 6(17), 11570-11584. https://doi.org/10.1021/acsomega.1c00779
Gao, Xia ; Zhang, Huanhuan ; Guan, Jingying 等. / Pomegranate-like Core-Shell Ni-NSs@MSNSs as a High Activity, Good Stability, Rapid Magnetic Separation, and Multiple Recyclability Nanocatalyst for DCPD Hydrogenation. 在: ACS Omega. 2021 ; 卷 6, 号码 17. 页码 11570-11584.
@article{8db1af6dccad44caa40081a10b985fcc,
title = "Pomegranate-like Core-Shell Ni-NSs@MSNSs as a High Activity, Good Stability, Rapid Magnetic Separation, and Multiple Recyclability Nanocatalyst for DCPD Hydrogenation",
abstract = "A novel pomegranate-like Ni-NSs@MSNSs nanocatalyst was successfully synthesized via a modified St{\"o}ber method, and its application in the hydrogenation of dicyclopentadiene (DCPD) was firstly reported. The Ni-NSs@MSNSs possessed a high specific area (658 m2/g) and mesoporous structure (1.7-3.3 nm). The reaction of hydrogenation of DCPD to endo-tetrahydrodicyclopentadiene (endo-THDCPD) was used to evaluate the catalytic performance of the prepared materials. The distinctive pomegranate-like Ni-NSs@MSNSs core-shell nanocomposite exhibited superior catalytic activity (TOF = 106.0 h-1 and STY = 112.7 g·L-1·h-1) and selectivity (98.9%) than conventional Ni-based catalysts (experimental conditions: Ni/DCPD/cyclohexane = 1/100/1000 (w/w), 150 °C, and 2.5 MPa). Moreover, the Ni-NSs@MSNSs nanocatalyst could be rapidly and conveniently recycled by magnetic separation without appreciable loss. The Ni-NSs@MSNSs also exhibited excellent thermal stability (≥750 °C) and good recycling performance (without an activity and selectivity decrease in four runs). The superior application performance of the Ni-NSs@MSNSs nanocatalyst was mainly owing to its unique pomegranate-like structure and core-shell synergistic confinement effect.",
author = "Xia Gao and Huanhuan Zhang and Jingying Guan and Daxin Shi and Qin Wu and Chen, {Kang Cheng} and Yaoyuan Zhang and Caihong Feng and Yun Zhao and Qingze Jiao and Hansheng Li",
note = "Publisher Copyright: {\textcopyright} Authors 2021",
year = "2021",
month = may,
day = "4",
doi = "10.1021/acsomega.1c00779",
language = "English",
volume = "6",
pages = "11570--11584",
journal = "ACS Omega",
issn = "2470-1343",
publisher = "American Chemical Society",
number = "17",
}
Gao, X, Zhang, H, Guan, J, Shi, D, Wu, Q, Chen, KC, Zhang, Y, Feng, C, Zhao, Y, Jiao, Q & Li, H 2021, 'Pomegranate-like Core-Shell Ni-NSs@MSNSs as a High Activity, Good Stability, Rapid Magnetic Separation, and Multiple Recyclability Nanocatalyst for DCPD Hydrogenation', ACS Omega, 卷 6, 号码 17, 页码 11570-11584. https://doi.org/10.1021/acsomega.1c00779
Pomegranate-like Core-Shell Ni-NSs@MSNSs as a High Activity, Good Stability, Rapid Magnetic Separation, and Multiple Recyclability Nanocatalyst for DCPD Hydrogenation. / Gao, Xia; Zhang, Huanhuan; Guan, Jingying 等.
在:
ACS Omega, 卷 6, 号码 17, 04.05.2021, 页码 11570-11584.
科研成果: 期刊稿件 › 文章 › 同行评审
TY - JOUR
T1 - Pomegranate-like Core-Shell Ni-NSs@MSNSs as a High Activity, Good Stability, Rapid Magnetic Separation, and Multiple Recyclability Nanocatalyst for DCPD Hydrogenation
AU - Gao, Xia
AU - Zhang, Huanhuan
AU - Guan, Jingying
AU - Shi, Daxin
AU - Wu, Qin
AU - Chen, Kang Cheng
AU - Zhang, Yaoyuan
AU - Feng, Caihong
AU - Zhao, Yun
AU - Jiao, Qingze
AU - Li, Hansheng
N1 - Publisher Copyright:
© Authors 2021
PY - 2021/5/4
Y1 - 2021/5/4
N2 - A novel pomegranate-like Ni-NSs@MSNSs nanocatalyst was successfully synthesized via a modified Stöber method, and its application in the hydrogenation of dicyclopentadiene (DCPD) was firstly reported. The Ni-NSs@MSNSs possessed a high specific area (658 m2/g) and mesoporous structure (1.7-3.3 nm). The reaction of hydrogenation of DCPD to endo-tetrahydrodicyclopentadiene (endo-THDCPD) was used to evaluate the catalytic performance of the prepared materials. The distinctive pomegranate-like Ni-NSs@MSNSs core-shell nanocomposite exhibited superior catalytic activity (TOF = 106.0 h-1 and STY = 112.7 g·L-1·h-1) and selectivity (98.9%) than conventional Ni-based catalysts (experimental conditions: Ni/DCPD/cyclohexane = 1/100/1000 (w/w), 150 °C, and 2.5 MPa). Moreover, the Ni-NSs@MSNSs nanocatalyst could be rapidly and conveniently recycled by magnetic separation without appreciable loss. The Ni-NSs@MSNSs also exhibited excellent thermal stability (≥750 °C) and good recycling performance (without an activity and selectivity decrease in four runs). The superior application performance of the Ni-NSs@MSNSs nanocatalyst was mainly owing to its unique pomegranate-like structure and core-shell synergistic confinement effect.
AB - A novel pomegranate-like Ni-NSs@MSNSs nanocatalyst was successfully synthesized via a modified Stöber method, and its application in the hydrogenation of dicyclopentadiene (DCPD) was firstly reported. The Ni-NSs@MSNSs possessed a high specific area (658 m2/g) and mesoporous structure (1.7-3.3 nm). The reaction of hydrogenation of DCPD to endo-tetrahydrodicyclopentadiene (endo-THDCPD) was used to evaluate the catalytic performance of the prepared materials. The distinctive pomegranate-like Ni-NSs@MSNSs core-shell nanocomposite exhibited superior catalytic activity (TOF = 106.0 h-1 and STY = 112.7 g·L-1·h-1) and selectivity (98.9%) than conventional Ni-based catalysts (experimental conditions: Ni/DCPD/cyclohexane = 1/100/1000 (w/w), 150 °C, and 2.5 MPa). Moreover, the Ni-NSs@MSNSs nanocatalyst could be rapidly and conveniently recycled by magnetic separation without appreciable loss. The Ni-NSs@MSNSs also exhibited excellent thermal stability (≥750 °C) and good recycling performance (without an activity and selectivity decrease in four runs). The superior application performance of the Ni-NSs@MSNSs nanocatalyst was mainly owing to its unique pomegranate-like structure and core-shell synergistic confinement effect.
UR - http://www.scopus.com/inward/record.url?scp=85106708730&partnerID=8YFLogxK
U2 - 10.1021/acsomega.1c00779
DO - 10.1021/acsomega.1c00779
M3 - Article
AN - SCOPUS:85106708730
SN - 2470-1343
VL - 6
SP - 11570
EP - 11584
JO - ACS Omega
JF - ACS Omega
IS - 17
ER -
Gao X, Zhang H, Guan J, Shi D, Wu Q, Chen KC 等. Pomegranate-like Core-Shell Ni-NSs@MSNSs as a High Activity, Good Stability, Rapid Magnetic Separation, and Multiple Recyclability Nanocatalyst for DCPD Hydrogenation. ACS Omega. 2021 5月 4;6(17):11570-11584. doi: 10.1021/acsomega.1c00779