Poly(polyoxometalate)s assembled by (Ni6PW9) units: From ring-shaped Ni24-tetramers to rod-shaped Ni40-octamers

Ling Huang; Jie Zhang; Lin Cheng; Guo Yu Yang

doi:10.1039/c2cc34332k

Poly(polyoxometalate)s assembled by (Ni₆PW₉) units: From ring-shaped Ni₂₄-tetramers to rod-shaped Ni₄₀-octamers

Ling Huang, Jie Zhang, Lin Cheng, Guo Yu Yang^*

^*此作品的通讯作者

化学与化工学院

CAS - Fujian Institute of Research on the Structure of Matter

科研成果: 期刊稿件 › 文章 › 同行评审

68 引用（Scopus）

摘要

Both structure-directing effect and synergistic-directing effect of PW₉O₃₄ fragments result in two poly(polyoxotungstate)s (poly(POT)s) of the Ni₂₄-based tetramer with largest transition metal atoms among ring-shaped poly(POT) tetramers and the Ni₄₀-based poly(POT) octamer with the highest number of Ni ions among all known poly(POT)s to date, respectively.

源语言	英语
页（从-至）	9658-9660
页数	3
期刊	Chemical Communications
卷	48
期	77
DOI	https://doi.org/10.1039/c2cc34332k
出版状态	已出版 - 29 8月 2012

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title = "Poly(polyoxometalate)s assembled by (Ni6PW9) units: From ring-shaped Ni24-tetramers to rod-shaped Ni40-octamers",

abstract = "Both structure-directing effect and synergistic-directing effect of PW9O34 fragments result in two poly(polyoxotungstate)s (poly(POT)s) of the Ni24-based tetramer with largest transition metal atoms among ring-shaped poly(POT) tetramers and the Ni40-based poly(POT) octamer with the highest number of Ni ions among all known poly(POT)s to date, respectively.",

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AU - Zhang, Jie

AU - Cheng, Lin

AU - Yang, Guo Yu

PY - 2012/8/29

Y1 - 2012/8/29

N2 - Both structure-directing effect and synergistic-directing effect of PW9O34 fragments result in two poly(polyoxotungstate)s (poly(POT)s) of the Ni24-based tetramer with largest transition metal atoms among ring-shaped poly(POT) tetramers and the Ni40-based poly(POT) octamer with the highest number of Ni ions among all known poly(POT)s to date, respectively.

AB - Both structure-directing effect and synergistic-directing effect of PW9O34 fragments result in two poly(polyoxotungstate)s (poly(POT)s) of the Ni24-based tetramer with largest transition metal atoms among ring-shaped poly(POT) tetramers and the Ni40-based poly(POT) octamer with the highest number of Ni ions among all known poly(POT)s to date, respectively.

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Poly(polyoxometalate)s assembled by (Ni6PW9) units: From ring-shaped Ni24-tetramers to rod-shaped Ni40-octamers

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Poly(polyoxometalate)s assembled by (Ni₆PW₉) units: From ring-shaped Ni₂₄-tetramers to rod-shaped Ni₄₀-octamers