Polymeric disodium (/i-fra/is-4,4′-ethylene-dipyridyl)bis[μ-5- sulfoisophthalato(3-)]-dicadmate(II) hexahydrate

Jun Tao; Xin Yin; Rong Bin Huang; Lan Sun Zheng; Seik Weng Ng

doi:10.1107/S1600536803015289

Polymeric disodium (/i-fra/is-4,4′-ethylene-dipyridyl)bis[μ-5- sulfoisophthalato(3-)]-dicadmate(II) hexahydrate

Jun Tao, Xin Yin, Rong Bin Huang, Lan Sun Zheng, Seik Weng Ng^*

^*此作品的通讯作者

科研成果: 期刊稿件 › 文章 › 同行评审

9 引用（Scopus）

摘要

The title crystal structure, (Na₂[Cd₂(C ₁₂H₁₀N₂)(C₈H₃O ₇S)₂]·-6H₂O)_n, contains pentagonal-bipyramidal Cd atoms and octahedral Na atoms. The Cd atom is chelated by two carboxyl groups of adjacent 5-sulfoisophthalate(3-) trianions, and it is also coordinated by the pyridyl group of the centrosymmetric heterocycle, the coordinating atoms comprising the pentagonal plane around the metal atom. In the network structure, the Na atoms occupy the voids in the network such that they exist in a six-coordinate geometry.

源语言	英语
页（从-至）	m611-m613
期刊	Acta Crystallographica Section E: Structure Reports Online
卷	59
期	8
DOI	https://doi.org/10.1107/S1600536803015289
出版状态	已出版 - 8月 2003
已对外发布	是

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title = "Polymeric disodium (/i-fra/is-4,4′-ethylene-dipyridyl)bis[μ-5- sulfoisophthalato(3-)]-dicadmate(II) hexahydrate",

abstract = "The title crystal structure, (Na2[Cd2(C 12H10N2)(C8H3O 7S)2]·-6H2O)n, contains pentagonal-bipyramidal Cd atoms and octahedral Na atoms. The Cd atom is chelated by two carboxyl groups of adjacent 5-sulfoisophthalate(3-) trianions, and it is also coordinated by the pyridyl group of the centrosymmetric heterocycle, the coordinating atoms comprising the pentagonal plane around the metal atom. In the network structure, the Na atoms occupy the voids in the network such that they exist in a six-coordinate geometry.",

author = "Jun Tao and Xin Yin and Huang, {Rong Bin} and Zheng, {Lan Sun} and Ng, {Seik Weng}",

year = "2003",

month = aug,

doi = "10.1107/S1600536803015289",

language = "English",

volume = "59",

pages = "m611--m613",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "8",

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T1 - Polymeric disodium (/i-fra/is-4,4′-ethylene-dipyridyl)bis[μ-5- sulfoisophthalato(3-)]-dicadmate(II) hexahydrate

AU - Tao, Jun

AU - Yin, Xin

AU - Huang, Rong Bin

AU - Zheng, Lan Sun

AU - Ng, Seik Weng

PY - 2003/8

Y1 - 2003/8

N2 - The title crystal structure, (Na2[Cd2(C 12H10N2)(C8H3O 7S)2]·-6H2O)n, contains pentagonal-bipyramidal Cd atoms and octahedral Na atoms. The Cd atom is chelated by two carboxyl groups of adjacent 5-sulfoisophthalate(3-) trianions, and it is also coordinated by the pyridyl group of the centrosymmetric heterocycle, the coordinating atoms comprising the pentagonal plane around the metal atom. In the network structure, the Na atoms occupy the voids in the network such that they exist in a six-coordinate geometry.

AB - The title crystal structure, (Na2[Cd2(C 12H10N2)(C8H3O 7S)2]·-6H2O)n, contains pentagonal-bipyramidal Cd atoms and octahedral Na atoms. The Cd atom is chelated by two carboxyl groups of adjacent 5-sulfoisophthalate(3-) trianions, and it is also coordinated by the pyridyl group of the centrosymmetric heterocycle, the coordinating atoms comprising the pentagonal plane around the metal atom. In the network structure, the Na atoms occupy the voids in the network such that they exist in a six-coordinate geometry.

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U2 - 10.1107/S1600536803015289

DO - 10.1107/S1600536803015289

M3 - Article

AN - SCOPUS:8144221335

SN - 1600-5368

VL - 59

SP - m611-m613

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 8

ER -

Polymeric disodium (/i-fra/is-4,4′-ethylene-dipyridyl)bis[μ-5- sulfoisophthalato(3-)]-dicadmate(II) hexahydrate

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