Photochemistry of nonconjugated bichromophoric systems III. Synthesis and photoreaction of poly(ethylene glycol) biscoumarinyloxyacetates

Yong Mei Wang; Da Ming Du; Ji Ben Meng; Xiu Zhong Zhou; Lei Wang

doi:10.1002/cjoc.19970150212

Photochemistry of nonconjugated bichromophoric systems III. Synthesis and photoreaction of poly(ethylene glycol) biscoumarinyloxyacetates

Yong Mei Wang, Da Ming Du, Ji Ben Meng^*, Xiu Zhong Zhou, Lei Wang

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摘要

A series of poly(ethylene glycol) biscoumarinyloxyacetates have been synthesized and their intramolecular photochemical cyclodimerizations have been studied. It was found that only syn-HT configuration products were obtained when these bisesters were directly irradiated in chloroform, and the yields of the products decreased with the increase of the chain length. This photocyclization reaction is a convenient and effective method to synthesize macrocyclic compounds.

源语言	英语
页（从-至）	169-173
页数	5
期刊	Chinese Journal of Chemistry
卷	15
期	2
DOI	https://doi.org/10.1002/cjoc.19970150212
出版状态	已出版 - 1997
已对外发布	是

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title = "Photochemistry of nonconjugated bichromophoric systems III. Synthesis and photoreaction of poly(ethylene glycol) biscoumarinyloxyacetates",

abstract = "A series of poly(ethylene glycol) biscoumarinyloxyacetates have been synthesized and their intramolecular photochemical cyclodimerizations have been studied. It was found that only syn-HT configuration products were obtained when these bisesters were directly irradiated in chloroform, and the yields of the products decreased with the increase of the chain length. This photocyclization reaction is a convenient and effective method to synthesize macrocyclic compounds.",

keywords = "Intramolecular cyclodimerization, Photochemistry, Poly(ethylene glycol) biscoumarinyloxyacetate",

author = "Wang, {Yong Mei} and Du, {Da Ming} and Meng, {Ji Ben} and Zhou, {Xiu Zhong} and Lei Wang",

year = "1997",

doi = "10.1002/cjoc.19970150212",

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AU - Wang, Yong Mei

AU - Du, Da Ming

AU - Meng, Ji Ben

AU - Zhou, Xiu Zhong

AU - Wang, Lei

PY - 1997

Y1 - 1997

N2 - A series of poly(ethylene glycol) biscoumarinyloxyacetates have been synthesized and their intramolecular photochemical cyclodimerizations have been studied. It was found that only syn-HT configuration products were obtained when these bisesters were directly irradiated in chloroform, and the yields of the products decreased with the increase of the chain length. This photocyclization reaction is a convenient and effective method to synthesize macrocyclic compounds.

AB - A series of poly(ethylene glycol) biscoumarinyloxyacetates have been synthesized and their intramolecular photochemical cyclodimerizations have been studied. It was found that only syn-HT configuration products were obtained when these bisesters were directly irradiated in chloroform, and the yields of the products decreased with the increase of the chain length. This photocyclization reaction is a convenient and effective method to synthesize macrocyclic compounds.

KW - Intramolecular cyclodimerization

KW - Photochemistry

KW - Poly(ethylene glycol) biscoumarinyloxyacetate

UR - http://www.scopus.com/inward/record.url?scp=0346573119&partnerID=8YFLogxK

U2 - 10.1002/cjoc.19970150212

DO - 10.1002/cjoc.19970150212

M3 - Article

AN - SCOPUS:0346573119

SN - 1001-604X

VL - 15

SP - 169

EP - 173

JO - Chinese Journal of Chemistry

JF - Chinese Journal of Chemistry

IS - 2

ER -

Photochemistry of nonconjugated bichromophoric systems III. Synthesis and photoreaction of poly(ethylene glycol) biscoumarinyloxyacetates

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