TY - JOUR
T1 - Pentaethylenehexaminemanganese(II) pentaborate
AU - Zhang, Hong Xia
AU - Zheng, Shou Tian
AU - Yang, Guo Yu
PY - 2004/6
Y1 - 2004/6
N2 - The title compound, (pentaethylenehexamine-κ6N) manganese(II) 4,4′,6,6′-tetrahydroxy-2,2′- spirobi(cyclotriboroxane)(1-), [Mn(C10H28N 6)][B5O6(OH)4]2, was synthesized under mild solvothermal conditions. The B5O 6(OH)4- units are connected to one another via hydrogen bonds, forming a three-dimensional framework with large channels along the a and c axes, in which the templating [Mn(C10H28N 6)]2- cations are located. The MnII complex cation has a twofold axis and the coordination geometry of the MnN6 group is that of a distorted trigonal prism.
AB - The title compound, (pentaethylenehexamine-κ6N) manganese(II) 4,4′,6,6′-tetrahydroxy-2,2′- spirobi(cyclotriboroxane)(1-), [Mn(C10H28N 6)][B5O6(OH)4]2, was synthesized under mild solvothermal conditions. The B5O 6(OH)4- units are connected to one another via hydrogen bonds, forming a three-dimensional framework with large channels along the a and c axes, in which the templating [Mn(C10H28N 6)]2- cations are located. The MnII complex cation has a twofold axis and the coordination geometry of the MnN6 group is that of a distorted trigonal prism.
UR - http://www.scopus.com/inward/record.url?scp=3142641344&partnerID=8YFLogxK
U2 - 10.1107/S0108270104007942
DO - 10.1107/S0108270104007942
M3 - Article
AN - SCOPUS:3142641344
SN - 0108-2701
VL - 60
SP - m241-m243
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 6
ER -