Organometallo-macrocycle assembled through dialumane-mediated C-H activation of pyridines

Weixing Chen; Li Liu; Yanxia Zhao; Yujie Xue; Wenhua Xu; Nan Li; Biao Wu; Xiao Juan Yang

doi:10.1039/d1cc00318f

Organometallo-macrocycle assembled through dialumane-mediated C-H activation of pyridines

Weixing Chen, Li Liu, Yanxia Zhao^*, Yujie Xue, Wenhua Xu, Nan Li^*, Biao Wu, Xiao Juan Yang^*

^*此作品的通讯作者

Northwest University China

科研成果: 期刊稿件 › 文章 › 同行评审

9 引用（Scopus）

摘要

Dialumane 1 reacts with pyridines at elevated temperatures through regioselective reductive dehydrogenation of 4-H, affording a unique hexanuclear Al(iii) macrocycle [{LAl(pyridyl)}6], which represents the first dialumane-mediated C-H activation of Py and may suggest a new approach toward organometallo supra-molecules by one-pot small molecule activation and self-assembly.

源语言	英语
页（从-至）	6268-6271
页数	4
期刊	Chemical Communications
卷	57
期	51
DOI	https://doi.org/10.1039/d1cc00318f
出版状态	已出版 - 28 6月 2021

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Chen, W., Liu, L., Zhao, Y., Xue, Y., Xu, W., Li, N., Wu, B., & Yang, X. J. (2021). Organometallo-macrocycle assembled through dialumane-mediated C-H activation of pyridines. Chemical Communications, 57(51), 6268-6271. https://doi.org/10.1039/d1cc00318f

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title = "Organometallo-macrocycle assembled through dialumane-mediated C-H activation of pyridines",

abstract = "Dialumane 1 reacts with pyridines at elevated temperatures through regioselective reductive dehydrogenation of 4-H, affording a unique hexanuclear Al(iii) macrocycle [{LAl(pyridyl)}6], which represents the first dialumane-mediated C-H activation of Py and may suggest a new approach toward organometallo supra-molecules by one-pot small molecule activation and self-assembly.",

author = "Weixing Chen and Li Liu and Yanxia Zhao and Yujie Xue and Wenhua Xu and Nan Li and Biao Wu and Yang, {Xiao Juan}",

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T1 - Organometallo-macrocycle assembled through dialumane-mediated C-H activation of pyridines

AU - Chen, Weixing

AU - Liu, Li

AU - Zhao, Yanxia

AU - Xue, Yujie

AU - Xu, Wenhua

AU - Li, Nan

AU - Wu, Biao

AU - Yang, Xiao Juan

PY - 2021/6/28

Y1 - 2021/6/28

N2 - Dialumane 1 reacts with pyridines at elevated temperatures through regioselective reductive dehydrogenation of 4-H, affording a unique hexanuclear Al(iii) macrocycle [{LAl(pyridyl)}6], which represents the first dialumane-mediated C-H activation of Py and may suggest a new approach toward organometallo supra-molecules by one-pot small molecule activation and self-assembly.

AB - Dialumane 1 reacts with pyridines at elevated temperatures through regioselective reductive dehydrogenation of 4-H, affording a unique hexanuclear Al(iii) macrocycle [{LAl(pyridyl)}6], which represents the first dialumane-mediated C-H activation of Py and may suggest a new approach toward organometallo supra-molecules by one-pot small molecule activation and self-assembly.

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U2 - 10.1039/d1cc00318f

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SN - 1359-7345

VL - 57

SP - 6268

EP - 6271

JO - Chemical Communications

JF - Chemical Communications

IS - 51

ER -

Organometallo-macrocycle assembled through dialumane-mediated C-H activation of pyridines

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