Organic aluminum hydrides catalyze nitrile hydroboration

Wenqing Liu, Yi Ding, Da Jin, Qiumiao Shen, Ben Yan, Xiaoli Ma*, Zhi Yang

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

60 引用 (Scopus)

摘要

Economical and eco-friendly aluminum hydrides were shown to be highly efficient catalysts for the solvent-free hydroboration of various nitriles using pinacolborane. The catalytic activities of three organic aluminum hydrides were compared. Mechanism investigation experiments revealed that nitrile was reduced to an imine intermediate by aluminum hydrides.

源语言英语
页(从-至)3812-3815
页数4
期刊Green Chemistry
21
14
DOI
出版状态已出版 - 2019

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