@article{a7ee001601984a9d9f0da05c7de2316f,
title = "On the origin of the surprisingly sluggish redox reaction of the N 2O/CO couple mediated by [Y2O2]+. and [YAlO2]+. cluster ions in the gas phase",
abstract = "Kinetic energy barriers that have entirely different origins are the reasons for the impedance of the catalytic N2O/CO redox cycle mediated by both [YAlO2]+. and [Y2O 2]+. clusters (see scheme). While oxidation with N 2O is the bottleneck for [YAlO2]+., oxidation of [Y2O2]+. with N2O is possible, but reduction of [Y2O3]+. by CO is prevented. This arises because of {"}doping{"} effects which can control local charges and spin distributions.",
keywords = "cluster ions, density functional caclculations, gas-phase reactions, homogeneous catalysis, ion-molecule reactions",
author = "Ma, {Jia Bi} and Wang, {Zhe Chen} and Maria Schlangen and He, {Sheng Gui} and Helmut Schwarz",
year = "2013",
month = jan,
day = "21",
doi = "10.1002/anie.201208559",
language = "English",
volume = "52",
pages = "1226--1230",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "4",
}