On the Curing Theory and the Scaling Study of the Polycondensation Reaction of Aa1…Aas—Bb1…Bbt Type

Au Chin Tang, Li Ze-sheng, Sun Chia-chung, Tang Xin-yi

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摘要

For the polycondensation reaction of Aa1…Aas—Bb1…Bbt type, the sol fraction above the gel point is investigated in detail by taking Stockmayers gelation condition as a criterion. Furthermore, the scaling behavior near the gel point is revealed to reach an asymptopic form of Stockmayers equilibrium number distribution from which a generalized scaling law is deduced.

源语言英语
页（从-至）797-804
页数8
期刊Macromolecules
卷21
期3
DOI
出版状态已出版 - 1988
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Tang, A. C., Ze-sheng, L., Chia-chung, S., & Xin-yi, T. (1988). On the Curing Theory and the Scaling Study of the Polycondensation Reaction of Aa1…Aas—Bb1…Bbt Type. Macromolecules, 21(3), 797-804. https://doi.org/10.1021/ma00181a041