Non-superimposable mirror image crystals of enantiomers by spontaneous resolution and the chiral discrimination mechanism

Muhammad Sohail; Yao Feng Wang; Shao Xiang Wu; Wei Zeng; Ji Yi Guo; Fu Xue Chen

doi:10.1016/j.cclet.2013.04.045

Non-superimposable mirror image crystals of enantiomers by spontaneous resolution and the chiral discrimination mechanism

Muhammad Sohail, Yao Feng Wang, Shao Xiang Wu, Wei Zeng, Ji Yi Guo, Fu Xue Chen^*

^*此作品的通讯作者

化学与化工学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

3 引用（Scopus）

摘要

Non-superimposable mirror image crystals of both enantiomers (S/R) of cyclic γ-alkenyl alcohol (2) have been recognized and remarkably identified by the naked eye. More interestingly, both crystals are an outcome of most astonishingly H-bond and intermolecular σ/π-π interactions. They accounted for the relatively rare and less predictable spontaneous resolution with optical purity >99% ee from the racemic mixture. The chiral discrimination mechanism of this spontaneous resolution has also been proposed.

源语言	英语
页（从-至）	695-698
页数	4
期刊	Chinese Chemical Letters
卷	24
期	8
DOI	https://doi.org/10.1016/j.cclet.2013.04.045
出版状态	已出版 - 8月 2013

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title = "Non-superimposable mirror image crystals of enantiomers by spontaneous resolution and the chiral discrimination mechanism",

abstract = "Non-superimposable mirror image crystals of both enantiomers (S/R) of cyclic γ-alkenyl alcohol (2) have been recognized and remarkably identified by the naked eye. More interestingly, both crystals are an outcome of most astonishingly H-bond and intermolecular σ/π-π interactions. They accounted for the relatively rare and less predictable spontaneous resolution with optical purity >99% ee from the racemic mixture. The chiral discrimination mechanism of this spontaneous resolution has also been proposed.",

keywords = "Mirror images, Octahydrobenzofuran, Preferential crystallization, Spontaneous resolution",

author = "Muhammad Sohail and Wang, {Yao Feng} and Wu, {Shao Xiang} and Wei Zeng and Guo, {Ji Yi} and Chen, {Fu Xue}",

year = "2013",

month = aug,

doi = "10.1016/j.cclet.2013.04.045",

language = "English",

volume = "24",

pages = "695--698",

journal = "Chinese Chemical Letters",

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T1 - Non-superimposable mirror image crystals of enantiomers by spontaneous resolution and the chiral discrimination mechanism

AU - Sohail, Muhammad

AU - Wang, Yao Feng

AU - Wu, Shao Xiang

AU - Zeng, Wei

AU - Guo, Ji Yi

AU - Chen, Fu Xue

PY - 2013/8

Y1 - 2013/8

N2 - Non-superimposable mirror image crystals of both enantiomers (S/R) of cyclic γ-alkenyl alcohol (2) have been recognized and remarkably identified by the naked eye. More interestingly, both crystals are an outcome of most astonishingly H-bond and intermolecular σ/π-π interactions. They accounted for the relatively rare and less predictable spontaneous resolution with optical purity >99% ee from the racemic mixture. The chiral discrimination mechanism of this spontaneous resolution has also been proposed.

AB - Non-superimposable mirror image crystals of both enantiomers (S/R) of cyclic γ-alkenyl alcohol (2) have been recognized and remarkably identified by the naked eye. More interestingly, both crystals are an outcome of most astonishingly H-bond and intermolecular σ/π-π interactions. They accounted for the relatively rare and less predictable spontaneous resolution with optical purity >99% ee from the racemic mixture. The chiral discrimination mechanism of this spontaneous resolution has also been proposed.

KW - Mirror images

KW - Octahydrobenzofuran

KW - Preferential crystallization

KW - Spontaneous resolution

UR - http://www.scopus.com/inward/record.url?scp=84879970963&partnerID=8YFLogxK

U2 - 10.1016/j.cclet.2013.04.045

DO - 10.1016/j.cclet.2013.04.045

M3 - Article

AN - SCOPUS:84879970963

SN - 1001-8417

VL - 24

SP - 695

EP - 698

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 8

ER -

Non-superimposable mirror image crystals of enantiomers by spontaneous resolution and the chiral discrimination mechanism

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