TY - JOUR
T1 - Non-fullerene acceptors with hetero-dihalogenated terminals induce significant difference in single crystallography and enable binary organic solar cells with 17.5% efficiency
AU - Wang, Lai
AU - An, Qiaoshi
AU - Yan, Lu
AU - Bai, Hai Rui
AU - Jiang, Mengyun
AU - Mahmood, Asif
AU - Yang, Can
AU - Zhi, Hongfu
AU - Wang, Jin Liang
N1 - Publisher Copyright:
© The Royal Society of Chemistry.
PY - 2022/1
Y1 - 2022/1
N2 - Despite the dihalogenation of terminals being an effective strategy to produce efficient nonfullerene acceptor (NFA)-based organic solar cells (OSCs), hetero-dihalogenated terminals are quite difficult to prepare. Here, we synthesized, for the first time, two new hetero-dihalogenated terminals (FCl-IC and FBr-IC) with a fluorine/chlorine or fluorine/bromine pair at one terminal and three NFAs (Y-BO-FCl, Y-BO-FBr, and Y-BO-ClBr) with three hetero-dihalogenated terminals (FCl-IC, FBr-IC, and ClBr-IC) using a general process for OSCs, respectively. A neat film of Y-BO-FCl presents a slightly lower energy level in comparison to those of Y-BO-FBr and Y-BO-ClBr. We, for the first time, obtained single crystals of hetero-dihalogenated NFAs. On going from Y-BO-ClBr single crystals to fluorinated acceptor single crystals, the crystal systems and intermolecular packing motifs were significantly improved. The crystallographic and theoretical analysis indicate that Y-BO-FCl exhibits the most planar molecular geometry, the shortest intermolecular packing distance and largest π-π electronic coupling among these acceptors. Moreover, PM6:Y-BO-FCl blend films present more ordered face-on orientation crystallinity, more suitable fiber-like phase separation, higher and more balanced charge mobility, and weaker charge recombination in comparison with those of PM6:Y-BO-FBr and PM6:Y-BO-ClBr. As a result, a performance of up to a remarkable power conversion efficiency of 17.52% with an enhanced FF value of ca. 78% was achieved in binary Y-BO-FCl:PM6 devices compared to those of PM6:Y-BO-FBr (16.47%) and PM6:Y-BO-ClBr (13.61%), which to date is the highest efficiency for a hetero-halogenated NFAs-based OSC. Our investigations demonstrate that a fluorine/chlorine hetero-dihalogenated terminal represents a new and effective synergistic strategy to induce significant differences in single crystals and produce high-performance hetero-halogenated NFA-based OSCs.
AB - Despite the dihalogenation of terminals being an effective strategy to produce efficient nonfullerene acceptor (NFA)-based organic solar cells (OSCs), hetero-dihalogenated terminals are quite difficult to prepare. Here, we synthesized, for the first time, two new hetero-dihalogenated terminals (FCl-IC and FBr-IC) with a fluorine/chlorine or fluorine/bromine pair at one terminal and three NFAs (Y-BO-FCl, Y-BO-FBr, and Y-BO-ClBr) with three hetero-dihalogenated terminals (FCl-IC, FBr-IC, and ClBr-IC) using a general process for OSCs, respectively. A neat film of Y-BO-FCl presents a slightly lower energy level in comparison to those of Y-BO-FBr and Y-BO-ClBr. We, for the first time, obtained single crystals of hetero-dihalogenated NFAs. On going from Y-BO-ClBr single crystals to fluorinated acceptor single crystals, the crystal systems and intermolecular packing motifs were significantly improved. The crystallographic and theoretical analysis indicate that Y-BO-FCl exhibits the most planar molecular geometry, the shortest intermolecular packing distance and largest π-π electronic coupling among these acceptors. Moreover, PM6:Y-BO-FCl blend films present more ordered face-on orientation crystallinity, more suitable fiber-like phase separation, higher and more balanced charge mobility, and weaker charge recombination in comparison with those of PM6:Y-BO-FBr and PM6:Y-BO-ClBr. As a result, a performance of up to a remarkable power conversion efficiency of 17.52% with an enhanced FF value of ca. 78% was achieved in binary Y-BO-FCl:PM6 devices compared to those of PM6:Y-BO-FBr (16.47%) and PM6:Y-BO-ClBr (13.61%), which to date is the highest efficiency for a hetero-halogenated NFAs-based OSC. Our investigations demonstrate that a fluorine/chlorine hetero-dihalogenated terminal represents a new and effective synergistic strategy to induce significant differences in single crystals and produce high-performance hetero-halogenated NFA-based OSCs.
UR - http://www.scopus.com/inward/record.url?scp=85122634001&partnerID=8YFLogxK
U2 - 10.1039/d1ee01832a
DO - 10.1039/d1ee01832a
M3 - Article
AN - SCOPUS:85122634001
SN - 1754-5692
VL - 15
SP - 320
EP - 333
JO - Energy and Environmental Science
JF - Energy and Environmental Science
IS - 1
ER -
