Nickel complexes with two types of noninnocent ligands: α-Diimine and phenazine

Qingsong Dong; Ji Hu Su; Shida Gong; Qian Shu Li; Yanxia Zhao; Biao Wu; Xiao Juan Yang

doi:10.1021/om400130m

Nickel complexes with two types of noninnocent ligands: α-Diimine and phenazine

Qingsong Dong, Ji Hu Su, Shida Gong, Qian Shu Li, Yanxia Zhao, Biao Wu, Xiao Juan Yang^*

^*此作品的通讯作者

科研成果: 期刊稿件 › 文章 › 同行评审

17 引用（Scopus）

摘要

The α-diimine nickel dibromo complex LNiBr₂ (L = [(2,6-iPr₂C₆H₃)NC(Me)]₂) reacts with various amounts of potassium metal and phenazine (Phz) to afford the complexes [LNi(η⁴-C₄-Phz)] (1) and [K(DME)]₂[(LNi) ₂(μ-η¹:η¹-N,N-Phz)] (2), in which the Phz molecule adopts significantly different coordination modes with different oxidation states of Phz, Ni, and L.

源语言	英语
页（从-至）	2866-2869
页数	4
期刊	Organometallics
卷	32
期	9
DOI	https://doi.org/10.1021/om400130m
出版状态	已出版 - 13 5月 2013
已对外发布	是

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@article{fd1581472d534cc1b70d816a9bdfaf33,

title = "Nickel complexes with two types of noninnocent ligands: α-Diimine and phenazine",

abstract = "The α-diimine nickel dibromo complex LNiBr2 (L = [(2,6-iPr2C6H3)NC(Me)]2) reacts with various amounts of potassium metal and phenazine (Phz) to afford the complexes [LNi(η4-C4-Phz)] (1) and [K(DME)]2[(LNi) 2(μ-η1:η1-N,N-Phz)] (2), in which the Phz molecule adopts significantly different coordination modes with different oxidation states of Phz, Ni, and L.",

author = "Qingsong Dong and Su, {Ji Hu} and Shida Gong and Li, {Qian Shu} and Yanxia Zhao and Biao Wu and Yang, {Xiao Juan}",

year = "2013",

month = may,

day = "13",

doi = "10.1021/om400130m",

language = "English",

volume = "32",

pages = "2866--2869",

journal = "Organometallics",

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TY - JOUR

T1 - Nickel complexes with two types of noninnocent ligands

T2 - α-Diimine and phenazine

AU - Dong, Qingsong

AU - Su, Ji Hu

AU - Gong, Shida

AU - Li, Qian Shu

AU - Zhao, Yanxia

AU - Wu, Biao

AU - Yang, Xiao Juan

PY - 2013/5/13

Y1 - 2013/5/13

N2 - The α-diimine nickel dibromo complex LNiBr2 (L = [(2,6-iPr2C6H3)NC(Me)]2) reacts with various amounts of potassium metal and phenazine (Phz) to afford the complexes [LNi(η4-C4-Phz)] (1) and [K(DME)]2[(LNi) 2(μ-η1:η1-N,N-Phz)] (2), in which the Phz molecule adopts significantly different coordination modes with different oxidation states of Phz, Ni, and L.

AB - The α-diimine nickel dibromo complex LNiBr2 (L = [(2,6-iPr2C6H3)NC(Me)]2) reacts with various amounts of potassium metal and phenazine (Phz) to afford the complexes [LNi(η4-C4-Phz)] (1) and [K(DME)]2[(LNi) 2(μ-η1:η1-N,N-Phz)] (2), in which the Phz molecule adopts significantly different coordination modes with different oxidation states of Phz, Ni, and L.

UR - http://www.scopus.com/inward/record.url?scp=84877731591&partnerID=8YFLogxK

U2 - 10.1021/om400130m

DO - 10.1021/om400130m

M3 - Article

AN - SCOPUS:84877731591

SN - 0276-7333

VL - 32

SP - 2866

EP - 2869

JO - Organometallics

JF - Organometallics

IS - 9

ER -

Nickel complexes with two types of noninnocent ligands: α-Diimine and phenazine

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