TY - JOUR
T1 - New Synthesis of 3,6-Dibromophthalonitrile and Phthalocyanine Having Eight Thienyl Substituents at Peripheral α-Positions
AU - Wang, Rongrong
AU - Zhao, Yan
AU - Zhu, Chunli
AU - Huang, Xuebin
N1 - Publisher Copyright:
© 2014 HeteroCorporation.
PY - 2015/7/1
Y1 - 2015/7/1
N2 - 3,6-Dibromophthalonitrile was successfully synthesized from 3,6-dihydroxyphthalonitrile using triphenylphosphine dibromide as bromation reagent. Starting from 3,6-dibromophthalonitrile, synthesis of 1,4,8,11,15,18,22,25-octakis(4-dodecylthiophen-2-yl)phthalocyaninatozinc(II) (ZnPc) was described. TGA demonstrated the perfect stability of ZnPc. The newly prepared ZnPc that was symmetrically substituted with thienyl substituents results in an intensively red-shifted Q-band. The HOMO and LUMO values of ZnPc were acquired by CV.
AB - 3,6-Dibromophthalonitrile was successfully synthesized from 3,6-dihydroxyphthalonitrile using triphenylphosphine dibromide as bromation reagent. Starting from 3,6-dibromophthalonitrile, synthesis of 1,4,8,11,15,18,22,25-octakis(4-dodecylthiophen-2-yl)phthalocyaninatozinc(II) (ZnPc) was described. TGA demonstrated the perfect stability of ZnPc. The newly prepared ZnPc that was symmetrically substituted with thienyl substituents results in an intensively red-shifted Q-band. The HOMO and LUMO values of ZnPc were acquired by CV.
UR - http://www.scopus.com/inward/record.url?scp=84938289663&partnerID=8YFLogxK
U2 - 10.1002/jhet.2130
DO - 10.1002/jhet.2130
M3 - Article
AN - SCOPUS:84938289663
SN - 0022-152X
VL - 52
SP - 1230
EP - 1233
JO - Journal of Heterocyclic Chemistry
JF - Journal of Heterocyclic Chemistry
IS - 4
ER -