Wang, J., Chen, X., Cai, Z., Luo, H., Li, Y., Liu, Z., Zhang, G., & Zhang, D. (2013). New alternating electron donor-acceptor conjugated polymers entailing (E)-[4,4′-biimidazolylidene]-5,5′(1H,1′H)-dione moieties. Polymer Chemistry, 4(20), 5283-5290. https://doi.org/10.1039/c3py00129f
Wang, Jianguo ; Chen, Xin ; Cai, Zhengxu 等. / New alternating electron donor-acceptor conjugated polymers entailing (E)-[4,4′-biimidazolylidene]-5,5′(1H,1′H)-dione moieties. 在: Polymer Chemistry. 2013 ; 卷 4, 号码 20. 页码 5283-5290.
@article{05b389568a954ff39472ecb3028e50bf,
title = "New alternating electron donor-acceptor conjugated polymers entailing (E)-[4,4′-biimidazolylidene]-5,5′(1H,1′H)-dione moieties",
abstract = "Four new alternating D-A polymers (P1-P4) with (E)-[4,4′- biimidazolylidene]-5,5′(1H,1′H)-dione (BID) as electron accepting moieties were synthesized and characterized. Based on GPC (gel permeation chromatography) data, Mws of P1-P4 are relatively high ranging from 11.8 to 14.7 kg mol-1 with polydispersities of 1.8-1.9. Thin-films of P1-P4 show broad and strong absorptions up to 950 nm. HOMO (-5.11 eV to -5.32 eV) and LUMO (-3.71 eV to -3.81 eV) energies as well as band gaps (1.40 eV to 1.53 eV) were determined based on their onset redox potentials and absorption spectra. Field-effect transistors with thin-films of P1-P4 were successfully fabricated with conventional techniques. The results reveal that thin-films of P1 and P2 exhibit relatively high hole mobilities of up to 6.6 × 10 -3 cm2 V-1 s-1.",
author = "Jianguo Wang and Xin Chen and Zhengxu Cai and Hewei Luo and Yonghai Li and Zitong Liu and Guanxin Zhang and Deqing Zhang",
year = "2013",
month = oct,
day = "21",
doi = "10.1039/c3py00129f",
language = "English",
volume = "4",
pages = "5283--5290",
journal = "Polymer Chemistry",
issn = "1759-9954",
publisher = "Royal Society of Chemistry",
number = "20",
}
Wang, J, Chen, X, Cai, Z, Luo, H, Li, Y, Liu, Z, Zhang, G & Zhang, D 2013, 'New alternating electron donor-acceptor conjugated polymers entailing (E)-[4,4′-biimidazolylidene]-5,5′(1H,1′H)-dione moieties', Polymer Chemistry, 卷 4, 号码 20, 页码 5283-5290. https://doi.org/10.1039/c3py00129f
New alternating electron donor-acceptor conjugated polymers entailing (E)-[4,4′-biimidazolylidene]-5,5′(1H,1′H)-dione moieties. / Wang, Jianguo; Chen, Xin
; Cai, Zhengxu 等.
在:
Polymer Chemistry, 卷 4, 号码 20, 21.10.2013, 页码 5283-5290.
科研成果: 期刊稿件 › 文章 › 同行评审
TY - JOUR
T1 - New alternating electron donor-acceptor conjugated polymers entailing (E)-[4,4′-biimidazolylidene]-5,5′(1H,1′H)-dione moieties
AU - Wang, Jianguo
AU - Chen, Xin
AU - Cai, Zhengxu
AU - Luo, Hewei
AU - Li, Yonghai
AU - Liu, Zitong
AU - Zhang, Guanxin
AU - Zhang, Deqing
PY - 2013/10/21
Y1 - 2013/10/21
N2 - Four new alternating D-A polymers (P1-P4) with (E)-[4,4′- biimidazolylidene]-5,5′(1H,1′H)-dione (BID) as electron accepting moieties were synthesized and characterized. Based on GPC (gel permeation chromatography) data, Mws of P1-P4 are relatively high ranging from 11.8 to 14.7 kg mol-1 with polydispersities of 1.8-1.9. Thin-films of P1-P4 show broad and strong absorptions up to 950 nm. HOMO (-5.11 eV to -5.32 eV) and LUMO (-3.71 eV to -3.81 eV) energies as well as band gaps (1.40 eV to 1.53 eV) were determined based on their onset redox potentials and absorption spectra. Field-effect transistors with thin-films of P1-P4 were successfully fabricated with conventional techniques. The results reveal that thin-films of P1 and P2 exhibit relatively high hole mobilities of up to 6.6 × 10 -3 cm2 V-1 s-1.
AB - Four new alternating D-A polymers (P1-P4) with (E)-[4,4′- biimidazolylidene]-5,5′(1H,1′H)-dione (BID) as electron accepting moieties were synthesized and characterized. Based on GPC (gel permeation chromatography) data, Mws of P1-P4 are relatively high ranging from 11.8 to 14.7 kg mol-1 with polydispersities of 1.8-1.9. Thin-films of P1-P4 show broad and strong absorptions up to 950 nm. HOMO (-5.11 eV to -5.32 eV) and LUMO (-3.71 eV to -3.81 eV) energies as well as band gaps (1.40 eV to 1.53 eV) were determined based on their onset redox potentials and absorption spectra. Field-effect transistors with thin-films of P1-P4 were successfully fabricated with conventional techniques. The results reveal that thin-films of P1 and P2 exhibit relatively high hole mobilities of up to 6.6 × 10 -3 cm2 V-1 s-1.
UR - http://www.scopus.com/inward/record.url?scp=84884295141&partnerID=8YFLogxK
U2 - 10.1039/c3py00129f
DO - 10.1039/c3py00129f
M3 - Article
AN - SCOPUS:84884295141
SN - 1759-9954
VL - 4
SP - 5283
EP - 5290
JO - Polymer Chemistry
JF - Polymer Chemistry
IS - 20
ER -
Wang J, Chen X, Cai Z, Luo H, Li Y, Liu Z 等. New alternating electron donor-acceptor conjugated polymers entailing (E)-[4,4′-biimidazolylidene]-5,5′(1H,1′H)-dione moieties. Polymer Chemistry. 2013 10月 21;4(20):5283-5290. doi: 10.1039/c3py00129f
