Narcissistic self-sorting in anion-coordination-driven assemblies

Xiaotong Zhao; Heng Wang; Boyang Li; Bo Zheng; Dong Yang; Wenhua Xu; Xiaopeng Li; Xiao Juan Yang; Biao Wu

doi:10.1039/d1cc01652k

Narcissistic self-sorting in anion-coordination-driven assemblies

Xiaotong Zhao, Heng Wang, Boyang Li, Bo Zheng, Dong Yang, Wenhua Xu, Xiaopeng Li, Xiao Juan Yang, Biao Wu^*

^*此作品的通讯作者

科研成果: 期刊稿件 › 文章 › 同行评审

16 引用（Scopus）

摘要

Three tris-bis(urea) ligands with triphenylamine-basedC₃-symmetric spacers were synthesized, which assembled with sulfate or phosphate to form anionicA₃L₂pinwheel helices (A = anion and L = ligand) andA₄L₄tetrahedra, respectively. Interestingly, narcissistic self-sorting was observed in both structures from the mixture of the ligands, wherein each assembly contains only one type of ligand with no detectable mixed-ligand product as confirmed by the NMR and MS studies.

源语言	英语
页（从-至）	6078-6081
页数	4
期刊	Chemical Communications
卷	57
期	49
DOI	https://doi.org/10.1039/d1cc01652k
出版状态	已出版 - 21 6月 2021
已对外发布	是

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title = "Narcissistic self-sorting in anion-coordination-driven assemblies",

abstract = "Three tris-bis(urea) ligands with triphenylamine-basedC3-symmetric spacers were synthesized, which assembled with sulfate or phosphate to form anionicA3L2pinwheel helices (A = anion and L = ligand) andA4L4tetrahedra, respectively. Interestingly, narcissistic self-sorting was observed in both structures from the mixture of the ligands, wherein each assembly contains only one type of ligand with no detectable mixed-ligand product as confirmed by the NMR and MS studies.",

author = "Xiaotong Zhao and Heng Wang and Boyang Li and Bo Zheng and Dong Yang and Wenhua Xu and Xiaopeng Li and Yang, {Xiao Juan} and Biao Wu",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021.",

year = "2021",

month = jun,

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doi = "10.1039/d1cc01652k",

language = "English",

volume = "57",

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T1 - Narcissistic self-sorting in anion-coordination-driven assemblies

AU - Zhao, Xiaotong

AU - Wang, Heng

AU - Li, Boyang

AU - Zheng, Bo

AU - Yang, Dong

AU - Xu, Wenhua

AU - Li, Xiaopeng

AU - Yang, Xiao Juan

AU - Wu, Biao

PY - 2021/6/21

Y1 - 2021/6/21

N2 - Three tris-bis(urea) ligands with triphenylamine-basedC3-symmetric spacers were synthesized, which assembled with sulfate or phosphate to form anionicA3L2pinwheel helices (A = anion and L = ligand) andA4L4tetrahedra, respectively. Interestingly, narcissistic self-sorting was observed in both structures from the mixture of the ligands, wherein each assembly contains only one type of ligand with no detectable mixed-ligand product as confirmed by the NMR and MS studies.

AB - Three tris-bis(urea) ligands with triphenylamine-basedC3-symmetric spacers were synthesized, which assembled with sulfate or phosphate to form anionicA3L2pinwheel helices (A = anion and L = ligand) andA4L4tetrahedra, respectively. Interestingly, narcissistic self-sorting was observed in both structures from the mixture of the ligands, wherein each assembly contains only one type of ligand with no detectable mixed-ligand product as confirmed by the NMR and MS studies.

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VL - 57

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EP - 6081

JO - Chemical Communications

JF - Chemical Communications

IS - 49

ER -

Narcissistic self-sorting in anion-coordination-driven assemblies

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