Zhu, S., Jin, X., Tan, W., Zhang, Y., Zhao, G., Wang, X., Yang, Y., Zhou, C., Tang, Z., Wu, X., Gong, X., Zhu, C., Chen, Q., Liu, Z., Song, P., Li, M., Hu, J., Liang, Q., Ding, Y., & Jiang, Y. (2024). Multiple Dynamic Hydrogen Bonding Networks Boost the Mechanical Stability of Flexible Perovskite Solar Cells. Advanced Functional Materials, 34(48), 文章 2408487. https://doi.org/10.1002/adfm.202408487
Zhu, Siyuan ; Jin, Xi ; Tan, Wenyan 等. / Multiple Dynamic Hydrogen Bonding Networks Boost the Mechanical Stability of Flexible Perovskite Solar Cells. 在: Advanced Functional Materials. 2024 ; 卷 34, 号码 48.
@article{9f138cfcd8e74d2c9aca7059fb76fd51,
title = "Multiple Dynamic Hydrogen Bonding Networks Boost the Mechanical Stability of Flexible Perovskite Solar Cells",
abstract = "Flexible perovskite solar cells often experience constant or cyclic bending during their service life. Catastrophic failure of devices may occur due to the crack of polycrystalline perovskite films and delamination at the perovskite and the substrate interfaces, posing a significant stability concern. Here, a multiple dynamic hydrogen bonding polymer network is developed to enhance the mechanical strength of flexible perovskite solar cells in two ways. The main chain of poly(acrylic acid) decreases the mismatch of the coefficient of thermal expansion between the perovskite and the substrate by 16.7% through its flexibility and spatial occupation. The dopamine branch chains provide multiple dynamic hydrogen bonding sites, which contribute to increased energy dissipation upon stress deformation and reduce Young's modulus of perovskite by 54.3%. The inverted flexible perovskite solar cells achieve a champion power conversion efficiency of 23.02% and retain 81.3% of the initial PCE over 2000 h under continuous 1-sun equivalent illumination. Moreover, devices show excellent mechanical stability by remaining 90.2% of the original value after 5000 bending cycles.",
keywords = "flexible, mechanical stability, perovskite, polymer, solar cells",
author = "Siyuan Zhu and Xi Jin and Wenyan Tan and Yu Zhang and Guijie Zhao and Xinyue Wang and Yuxuan Yang and Chao Zhou and Zhaoheng Tang and Xiaoxue Wu and Xueyuan Gong and Cheng Zhu and Qi Chen and Zonghao Liu and Peng Song and Minghua Li and Jinsong Hu and Qijie Liang and Yong Ding and Yan Jiang",
note = "Publisher Copyright: {\textcopyright} 2024 Wiley-VCH GmbH.",
year = "2024",
month = nov,
day = "26",
doi = "10.1002/adfm.202408487",
language = "English",
volume = "34",
journal = "Advanced Functional Materials",
issn = "1616-301X",
publisher = "Wiley-VCH Verlag",
number = "48",
}
Zhu, S, Jin, X, Tan, W, Zhang, Y, Zhao, G, Wang, X, Yang, Y, Zhou, C, Tang, Z, Wu, X, Gong, X, Zhu, C, Chen, Q, Liu, Z, Song, P, Li, M, Hu, J, Liang, Q, Ding, Y & Jiang, Y 2024, 'Multiple Dynamic Hydrogen Bonding Networks Boost the Mechanical Stability of Flexible Perovskite Solar Cells', Advanced Functional Materials, 卷 34, 号码 48, 2408487. https://doi.org/10.1002/adfm.202408487
Multiple Dynamic Hydrogen Bonding Networks Boost the Mechanical Stability of Flexible Perovskite Solar Cells. / Zhu, Siyuan; Jin, Xi; Tan, Wenyan 等.
在:
Advanced Functional Materials, 卷 34, 号码 48, 2408487, 26.11.2024.
科研成果: 期刊稿件 › 文章 › 同行评审
TY - JOUR
T1 - Multiple Dynamic Hydrogen Bonding Networks Boost the Mechanical Stability of Flexible Perovskite Solar Cells
AU - Zhu, Siyuan
AU - Jin, Xi
AU - Tan, Wenyan
AU - Zhang, Yu
AU - Zhao, Guijie
AU - Wang, Xinyue
AU - Yang, Yuxuan
AU - Zhou, Chao
AU - Tang, Zhaoheng
AU - Wu, Xiaoxue
AU - Gong, Xueyuan
AU - Zhu, Cheng
AU - Chen, Qi
AU - Liu, Zonghao
AU - Song, Peng
AU - Li, Minghua
AU - Hu, Jinsong
AU - Liang, Qijie
AU - Ding, Yong
AU - Jiang, Yan
N1 - Publisher Copyright:
© 2024 Wiley-VCH GmbH.
PY - 2024/11/26
Y1 - 2024/11/26
N2 - Flexible perovskite solar cells often experience constant or cyclic bending during their service life. Catastrophic failure of devices may occur due to the crack of polycrystalline perovskite films and delamination at the perovskite and the substrate interfaces, posing a significant stability concern. Here, a multiple dynamic hydrogen bonding polymer network is developed to enhance the mechanical strength of flexible perovskite solar cells in two ways. The main chain of poly(acrylic acid) decreases the mismatch of the coefficient of thermal expansion between the perovskite and the substrate by 16.7% through its flexibility and spatial occupation. The dopamine branch chains provide multiple dynamic hydrogen bonding sites, which contribute to increased energy dissipation upon stress deformation and reduce Young's modulus of perovskite by 54.3%. The inverted flexible perovskite solar cells achieve a champion power conversion efficiency of 23.02% and retain 81.3% of the initial PCE over 2000 h under continuous 1-sun equivalent illumination. Moreover, devices show excellent mechanical stability by remaining 90.2% of the original value after 5000 bending cycles.
AB - Flexible perovskite solar cells often experience constant or cyclic bending during their service life. Catastrophic failure of devices may occur due to the crack of polycrystalline perovskite films and delamination at the perovskite and the substrate interfaces, posing a significant stability concern. Here, a multiple dynamic hydrogen bonding polymer network is developed to enhance the mechanical strength of flexible perovskite solar cells in two ways. The main chain of poly(acrylic acid) decreases the mismatch of the coefficient of thermal expansion between the perovskite and the substrate by 16.7% through its flexibility and spatial occupation. The dopamine branch chains provide multiple dynamic hydrogen bonding sites, which contribute to increased energy dissipation upon stress deformation and reduce Young's modulus of perovskite by 54.3%. The inverted flexible perovskite solar cells achieve a champion power conversion efficiency of 23.02% and retain 81.3% of the initial PCE over 2000 h under continuous 1-sun equivalent illumination. Moreover, devices show excellent mechanical stability by remaining 90.2% of the original value after 5000 bending cycles.
KW - flexible
KW - mechanical stability
KW - perovskite
KW - polymer
KW - solar cells
UR - http://www.scopus.com/inward/record.url?scp=85199688525&partnerID=8YFLogxK
U2 - 10.1002/adfm.202408487
DO - 10.1002/adfm.202408487
M3 - Article
AN - SCOPUS:85199688525
SN - 1616-301X
VL - 34
JO - Advanced Functional Materials
JF - Advanced Functional Materials
IS - 48
M1 - 2408487
ER -
Zhu S, Jin X, Tan W, Zhang Y, Zhao G, Wang X 等. Multiple Dynamic Hydrogen Bonding Networks Boost the Mechanical Stability of Flexible Perovskite Solar Cells. Advanced Functional Materials. 2024 11月 26;34(48):2408487. doi: 10.1002/adfm.202408487